Gaseous Heptanethiol Removal by a Fe3+-Phenanthroline-Kaolinite Hybrid Material

Kaolinite functionalized by the mu-oxo Fe3+-phenanthroline complex (Fe(+3)Phen) was selected to test its ability to efficiently remove and store gaseous heptanethiol (HPT). Spectroscopic techniques, elemental analysis, and thermal analysis coupled with evolved gas mass spectrometry were employed to characterize the material before and after the exposure to the gas and to define the adsorption process. The amount of HPT trapped by the functionalized kaolinite after 60 days is 0.10940 moles per 100 g of kaolinite which, considering the amount of adsorbed Fe(+3)Phen (0.00114 moles per 100 g of kaolinite), means a thiol/Fe(3+)Phen molar ratio of about 100:1, a value much higher than those found in the past for Fe(+3)Phen functionalized montmorillonite and sepiolite. In addition, the process was found to be efficient also beyond 60 days. This significant removal of the smelly gas was explained by considering a continuous catalytic activity of Fe3+ toward the oxidation of thiol to disulfide.

Automated summary

Kaolinite functionalized with mu-oxo Fe3+-phenanthroline complex was found to efficiently remove and store gaseous heptanethiol. The continuous catalytic activity of Fe3+ towards the oxidation of thiol to disulfide explained the significant removal of the smelly gas and the high thiol/Fe(3+)Phen molar ratio.