Using a fluorine-free copper mesh with dynamically tunable wetting properties for high-flux separation of oil-water mixtures

Managing oily wastewater continues to be a significant challenge with the continuous rise in oil extraction and processing, necessitating new and improved technologies to separate oil from water. In this regard, smart materials provide controllable super-wettability to separate either oil or water from their mixture based on the chosen wetting properties of the material. However, several challenges facing smart materials include high cost, low separation fluxes, poor durability, and complex equipment for separation. This study demonstrates the use of a fluorine-free superhydrophobic/superoleophilic copper mesh fabricated using N-(2-Aminoethyl)-11-Aminoundecyltrimethoxysilane. Oil-water separation using this material allows separation fluxes exceeding 80,000 L/ m2/h, with separation efficiencies above 90%. This cost-effective and straightforward approach is also durable, as demonstrated via abrasion tests. More importantly, we demonstrate a simple strategy to reversibly switch the wettability of the copper mesh between hydrophilic/oleophobic and hydrophobic/oleophilic states. This strategy allows varying the static water contact angles between 150o and 0o. Consequently, oil can be separated from an oil-water mixture using the hydrophobic/oleophilic wetting state, while water can be separated from the oilwater mixture using the hydrophilic/oleophobic wetting state. With further development, this material can address oily wastewater produced in industrial applications and oil-spills.

Automated summary

The study presents a novel approach of using a fluorine-free superhydrophobic/superoleophilic copper mesh for efficient oil-water separation, achieving high separation fluxes and efficiencies. The material is cost-effective, durable, and demonstrates a simple strategy to switch between different wetting states for selective separation of oil and water. This technology has the potential to address oily wastewater challenges in industrial applications and oil-spill situations with further development.