Journal
JOURNAL OF ENERGY STORAGE
Volume 45, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.est.2021.103719
Keywords
Bipolar NiFe battery; Monopolar electrode; Graphite substrate; Ni-mesh substrate; Current collector; beta-nickel copper hydroxide cathode; Iron-copper anode
Categories
Funding
- Department of Science and Innovation of South Africa
- Eskom Holdings SOC Ltd [2002/015527/30]
- National Research Foundation of South Africa [121413, 130409]
- BMBF
- [FKZ 01LZ1715A-B]
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The use of bipolar electrodes in rechargeable batteries has advantages such as improving specific power, simplifying cell design, and reducing manufacturing costs, but there are still drawbacks. Developing high-performance materials and strategies for improvement are crucial for battery design. The current collector plays a significant role in mass production feasibility and is often overlooked in electrochemical energy storage devices.
The use of bipolar electrodes in rechargeable batteries can improve specific power, simplify cell design, and reduce manufacturing costs. However, bipolar-based batteries still suffer from many drawbacks. Therefore, developing high-performance active materials and developing improvement strategies encompassing the entire cell's design is essential. The current collector significantly impacts the viability of mass production; however, it is the most neglected feature of electrochemical energy storage devices. The current collector serves a dual purpose; it allows the movement of electrons among active electrode material and provides mechanical support. It can also act as transportation of current to terminals of the battery. This study constructed a novel bipolar battery cell utilizing graphite as a current collector, and its discharge capacities for Ni-Fe battery applications were evaluated. Monopolar NiFe cells, one using a graphite substrate current collector and the other using a Ni-mesh current collector, were used for comparison. The monopolar-based electrode coated onto a graphite substrate demonstrated a 29% (199 mAh/g) higher discharge capacity than the Ni-mesh-based electrode (142 mAh/g) after the 100th cycle. In contrast, the bipolar-based NiFe battery cell resulted in a discharge capacity of 158 mAh/g after the 100th cycle, corresponding to a coulombic efficiency of 72%.
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