Journal
CHEMISTRYSELECT
Volume 6, Issue 47, Pages 13664-13723Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202103357
Keywords
Pd-catalyzed C-H activation; Suzuki-Miyaura reaction; Stille-Migita reaction; Negishi reaction; Heck reaction; Sonogashira reaction; azulene
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Funding
- Alexander von Humboldt Foundation
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This research discusses the recent developments in the synthesis of azulene derivatives through Pd-catalyzed coupling techniques over the previous two decades, including various substitution and coupling methods involving different organic groups and reaction conditions.
Azulene derivatives have important physical and physicochemical features, as well as advantageous biological qualities. The metal-catalyzed processes have proven to be a highly practical method for azulene functionalization. The development in the synthesis of azulene derivatives, including (aryl)heteroaryl-substituted and hetero-fused azulene derivatives, through Pd-catalyzed coupling techniques over the previous two decades is discussed in this research. Alkyl-, alkenyl-, and alkynylazulenes synthesized via Pd-catalyzed cross-coupling processes are also included.
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