4.2 Article

g-C3N4/TiO2 nanocomposite photocatalyst for methylene blue photodegradation under visible light

Journal

APPLIED NANOSCIENCE
Volume 12, Issue 11, Pages 3197-3206

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s13204-021-02328-y

Keywords

Nanocomposite; Photocatalyst; Degradation; Dye; Visible light

Funding

  1. Malaysia Ministry of Higher Education [FRGS/1/2019/STG07/UMT/02/2]

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In this research, g-C3N4/TiO2 nanocomposite was prepared using a hydrothermal method and used as a photocatalyst for dye degradation. The characterization of g-C3N4/TiO2 showed the presence of anatase and rutile phases of TiO2 and layered structure of g-C3N4. The nanocomposite demonstrated higher photocatalytic activity compared to pure g-C3N4 and TiO2, degrading the dye under visible light.
In this research, the g-C3N4/TiO2 nanocomposite was prepared by a simple hydrothermal method and was used as photocatalyst for dye degradation. Prior to that, the g-C3N4/TiO2 was characterized by different analytical techniques such as FTIR, XRD, SEM, and nitrogen gas adsorption. Main functional groups of g-C3N4/TiO2 composite are shown in the FTIR spectrum. The XRD pattern reveals that the presence of anatase and rutile phases of TiO2 as well as layer stacking of conjugated aromatic and in-planar repeating triazine unit of g-C3N4. The SEM analysis shows the presence of 2D-layered structured of g-C3N4 and agglomerated spherical TiO2 particles (OD). The 2D/0D g-C3N4/TiO2 nanocomposite shows higher photocatalytic activity than pure g-C3N4 and TiO2, whereby 100% of MB was degraded under visible light after 2 h. This is attributed to their high surface area which is 273.32 mg(-1) and generation of more effective reactive oxygen species of center dot OH and center dot O-2 to degrade MB.

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