4.7 Article

Bioinspired solar anti-icing/de-icing surfaces based on phase-change materials

Journal

SCIENCE CHINA-MATERIALS
Volume 65, Issue 5, Pages 1369-1376

Publisher

SCIENCE PRESS
DOI: 10.1007/s40843-021-1888-7

Keywords

bioinspired; phase-change materials; anti-icing/deicing; solar energy; multifunctional

Funding

  1. National Natural Science Foundation of China [21875261, 51925307, 21733010]
  2. National Key Research and Development Program of China [2020YFE0100300, 2018YFA0208502]
  3. Key Research Program of Frontier Sciences, Chinese Academy of Sciences [ZDBS-LYSLH031]
  4. Youth Innovation Promotion Association of the Chinese Academy of Sciences [2018044]

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The study investigates a solar phase-change material (SPCM) composed of expanded graphite (EG)/paraffin/polydimethylsiloxane (PDMS) that can effectively collect and store solar energy for anti-icing/de-icing purposes. The SPCM surface demonstrates excellent anti-icing/de-icing properties, maintaining a high de-icing rate and long freeze-delay time even at ultra-low temperatures. This research provides a promising approach for utilizing solar energy in anti-icing/de-icing applications.
Solar anti-icing/de-icing is an environmentally friendly way to convert light energy into heat with the purpose of melting/removing ice. However, the inherent intermittency of solar irradiation limits the application of solar-thermal energy-conversion technologies, when continuous de-icing is required. Herein, we investigate a solar phase-change material (SPCM) that consists of expanded graphite (EG)/paraffin/polydimethylsiloxane (PDMS), which can not only perform the solar-thermal conversion but also release/store thermal energy. Under sunlight, the SPCM effectively collects and converts the light energy into thermal energy for later anti-icing/de-icing. To prepare for a no-light period, e.g., in the evening, the converted thermal energy can be stored in the SPCM using a phase transition. In this way, the energy can be released when needed to keep the temperature of a surface from freezing. The SPCM surface shows excellent anti-icing/de-icing properties such as a long droplet freeze-delay time (t(d) > 2 h), even at an ultra-low temperature (-40 degrees C), using only the light of one sun. This freeze-delay time is much longer than that for a surface without PCM. The tested SPCM surfaces show a high de-icing rate (2.21 kg m(-2) h(-1)) under real-life conditions. In addition, the SPCM shows a high de-icing rate and excellent durability. This study provides a promising route for the utilization of solar energy in anti-icing/de-icing applications.

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