Journal
FRONTIERS IN CHEMISTRY
Volume 10, Issue -, Pages -Publisher
FRONTIERS MEDIA SA
DOI: 10.3389/fchem.2022.818627
Keywords
aryldiazonium salts; difunctionalization; p-azophenols; one-step; metal-free
Categories
Funding
- National Natural Science Foundation of China [21976112, 21775092]
- National Key R and D Program of China [2019YFA0210100]
- Major Science and Technology Innovation Project of Shandong Province [2021ZDSYS09]
- Natural Science Foundation of Shandong Province of China [ZR2021MB031, ZR2020JQ10]
- China Postdoctoral Science Foundation [2020M682204]
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A novel difunctionalization of aryldiazonium salts was developed for the one-step generation of symmetric and asymmetric p-azophenols. This approach utilizes sequential regioselective aromatic C-O and C-N bond construction under mild reaction conditions, providing a new reaction strategy for the synthesis of p-azophenols.
A novel difunctionalization of aryldiazonium salts was realized for the one-step generation of symmetric and asymmetric p-azophenols. This approach is proceeded by the sequentially regioselective aromatic C-O and C-N bond construction under mild reaction conditions, unlocking a new reaction strategy to facilitate the synthesis of p-azophenols.
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