Hydrogenolysis of Glycerol to Propylene Glycol: Energy, Tech-Economic, and Environmental Studies

Hydrogenolysis of glycerol to propylene glycol represents one of the most promising technologies for biomass conversion to chemicals. However, conventional hydrogenolysis processes are often carried out under harsh H-2 pressures and temperatures, leading to intensive energy demands, fast catalyst deactivation, and potential safety risks during H-2 handling. Catalytic transfer hydrogenolysis (CTH) displays high energy and atom efficiency. We have studied a series novel solid catalysts for CTH of glycerol. In this work, detailed studies have been conducted on energy optimization, tech-economic analysis, and environmental impact for both processes. The key finding is that relatively less energy demands and capital investment are required for CTH process. CO2 emission per production of propylene glycol is much lower in the case of transfer hydrogenolysis. The outcome of this study could provide useful information for process design and implementation of novel hydrogenolysis technologies for other energy and environmental applications.

Automated summary

Hydrogenolysis of glycerol to propylene glycol is a promising biomass conversion technology. However, conventional hydrogenolysis processes are energy-intensive, catalyst deactivates quickly and safety risks exist. Catalytic transfer hydrogenolysis shows high energy and atom efficiency. We studied novel solid catalysts for glycerol transfer hydrogenolysis and found that it requires less energy and capital investment. This study provides valuable information for the design and implementation of novel hydrogenolysis technologies for other energy and environmental applications.