4.6 Review

The Kinetics Studies on Hydrolysis of Hemicellulose

Journal

FRONTIERS IN CHEMISTRY
Volume 9, Issue -, Pages -

Publisher

FRONTIERS MEDIA SA
DOI: 10.3389/fchem.2021.781291

Keywords

hemicellulose; hydrolysis; kinetics; oligosaccharides; acid; thermogravimetric analyzer

Funding

  1. National Key R&D Program of China [2019YFC1905901]
  2. National Research Foundation of Korea (NRF) - Korea government (MSIT), R&D program for Forest Science Technology [2019151D10-2023-0301]
  3. Korea Forest Service (Korea Forestry Promotion Institute)
  4. Ministry of SMEs and Startups (MSS, Korea) [S3030198]
  5. Korea Forestry Promotion Institute (KOFPI) [2019151D10-2023-0301] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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This article discussed various strategies and historical context of kinetic models in hemicellulose hydrolysis, with a focus on oligosaccharides, acid catalysts, and thermogravimetric analysis. The article also presented the issues and suggestions for kinetic models in hemicellulose hydrolysis, aiming to enhance the understanding of hemicellulose pyrolysis mechanism.
The kinetics studies is of great importance for the understanding of the mechanism of hemicellulose pyrolysis and expanding the applications of hemicellulose. In the past years, rapid progress has been paid on the kinetics studies of hemicellulose hydrolysis. In this article, we first introduced the hydrolysis of hemicelluloses via various strategies such as autohydrolysis, dilute acid hydrolysis, catalytic hydrolysis, and enzymatic hydrolysis. Then, the history of kinetic models during hemicellulose hydrolysis was summarized. Special attention was paid to the oligosaccharides as intermediates or substrates, acid as catalyst, and thermogravimetric as analyzer method during the hemicellulose hydrolysis. Furthermore, the problems and suggestions of kinetic models during hemicellulose hydrolysis was provided. It expected that this article will favor the understanding of the mechanism of hemicellulose pyrolysis.

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