Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 9, Issue 7, Pages 1982-1985Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qo00067a
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Funding
- Students Research Learning and Innovative Experimental Project of University of South China [2020208]
- National Key Research and Development Program of China [2021YFF0701700]
- National Natural Science Foundation [21971252, 21991122]
- Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province
- Jinan Science and Technology Bureau [2019GXRC021]
- Key Research Program of Frontier Sciences
- Chinese Academy of Sciences (CAS) [QYZDJSSWSLH049]
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A protocol for visible light mediated C-H trifluoromethylation of unactivated (hetero)arenes under blue LED irradiation has been developed. It enables the rapid construction of a range of CF3-containing (hetero)arenes in moderate to high yields from the readily accessible trifluoromethylsulfonyl-pyridinium salt (TFSP). This protocol is also suitable for nitrogen-containing aromatic heterocycles, which are potentially useful in medicinal chemistry.
A protocol for visible light mediated C-H trifluoromethylation of unactivated (hetero)arenes under blue LED irradiation has been developed. The reaction enables the rapid construction of a range of CF3-containing (hetero)arenes in moderate to high yields from the readily accessible trifluoromethylsulfonyl-pyridinium salt (TFSP). This protocol is also suitable for nitrogen-containing aromatic heterocycles, which are potentially useful in medicinal chemistry.
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