Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 9, Issue 4, Pages 1016-1022Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qo01721g
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Funding
- National Natural Science Foundation of China [21772046, 2193103, 22001038]
- Fuzhou University [510578]
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This paper presents a diastereoselective addition of arylboronic acids to alpha-keto N-tert-butanesulfinyl aldimines catalyzed by a Rh(i) catalyst, offering a practical method to obtain valuable chiral alpha-amino ketones with excellent diastereoselectivity. The reaction is characterized by operational simplicity, mild reaction conditions, and a broad substrate scope.
Herein we present a diastereoselective addition of arylboronic acids to alpha-keto N-tert-butanesulfinyl aldimines catalyzed by a Rh(i) catalyst. This reaction provides a practical method to obtain valuable chiral alpha-amino ketones with excellent diastereoselectivity, featuring operational simplicity, mild reaction conditions and a broad substrate scope.
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