4.6 Article

Simple Approach to Medical Grade Alumina and Zirconia Ceramics Surface Alteration via Acid Etching Treatment

Journal

CRYSTALS
Volume 11, Issue 10, Pages -

Publisher

MDPI
DOI: 10.3390/cryst11101232

Keywords

alumina; zirconia; surface treatment; bioceramics modification; medical applications

Funding

  1. ESF in Science without borders projects within the Operational Programme Research, Development and Education, Ministry of Education, Youth and Sport of the Czech Republic [CZ.02.2.69/0.0./0.0./16_027/0008463, SP2021/106, SP2021/90]
  2. ESF [CZ.02.1.01/0.0/0.0/17_049/00084 07]
  3. Polish Ministry of Science and Higher Education [07/020/BK_21/0067 (BK-293/RIB3/2021)]

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The surface modification of bioceramic powders is crucial for enhancing their interaction with other materials, and is key to their successful incorporation into composites and applications.
In order for bioceramics to be further used in composites and their applications, it is important to change the surface so that the inert material is ready to interact with another material. Medical grade alumina and zirconia ceramic powders have been chemically etched with three selected acidic mixtures. Powder samples were taken for characterization, which was the key to evaluating a successful surface change. Changes in morphology, together with chemical composition, were studied using scanning electron microscopy, phase composition using X-ray diffraction methods, and nitrogen adsorption/desorption isotherms are used to evaluate specific surface area and porosity. The application of HF negatively affected the morphology of the material and caused agglomeration. The most effective modification of ceramic powders was the application of a piranha solution to obtain a new surface and a satisfactory degree of agglomeration. The prepared micro-roughness of the etched ceramic would provide an improved surface of the material either for its next step of incorporation into the selected matrix or to directly aid in the attachment and proliferation of osteoblast cells.

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