High Crystalline Quality Conductive Polypyrrole Film Prepared by Interface Chemical Oxidation Polymerization Method

The authors report that polypyrrole (PPy) films with large area and high crystalline quality have been achieved using an interfacial chemical oxidation method. By dissolving different reactants in two immiscible solvents, the PPy is synthetized at the interface region of the two solutions. The PPy films have sharp XRD diffraction peaks, indicating that the molecular chains in the film are arranged in a high degree of order and that they reflect high crystalline quality. High crystal quality is also conducive to improving electrical conductivity. The conductivity of the as prepared PPy film is about 0.3 S/cm, and the carrier mobility is about 5 cm(2)/(Vs). In addition, the biggest advantage of this method is that the prepared PPy film has a large area and is easy to transfer to other substrates. This will confidently broaden the application of PPy in the future.

Automated summary

Polypyrrole films with large area and high crystalline quality have been successfully synthesized using an interfacial chemical oxidation method. The films exhibit sharp XRD diffraction peaks, indicating high degree of molecular chain order and excellent crystalline quality. The as prepared films have a conductivity of about 0.3 S/cm and a carrier mobility of about 5 cm(2)/(Vs). The method also allows for easy transfer of the films to other substrates.