CoNiO2/Co4N Heterostructure Nanowires Assisted Polysulfide Reaction Kinetics for Improved Lithium-Sulfur Batteries

The shuttle effect of soluble polysulfides and slow reaction kinetics hinder the practical application of Li-S batteries. Transition metal oxides are promising mediators to alleviate these problems, but the poor electrical conductivity limits their further development. Herein, the homogeneous CoNiO2/Co4N nanowires have been fabricated and employed as additive of graphene based sulfur cathode. Through optimizing the nitriding degree, the continuous heterostructure interface can be obtained, accompanied by effective adjustment of energy band structure. By combining the strong adsorptive and catalytic properties of CoNiO2 and electrical conductivity of Co4N, the in situ formed CoNiO2/Co4N heterostructure reveals a synergistic enhancement effect. Theoretical calculation and experimental design show that it can not only significantly inhibit shuttle effect through chemisorption and catalytic conversion of polysulfides, but also improve the transport rate of ions and electrons. Thus, the graphene composite sulfur cathode supported by these CoNiO2/Co4N nanowires exhibits improved sulfur species reaction kinetics. The corresponding cell provides a high rate capacity of 688 mAh g(-1) at 4 C with an ultralow decaying rate of approximate to 0.07% per cycle over 600 cycles. The design of heterostructure nanowires and graphene composite structure provides an advanced strategy for the rapid capture-diffusion-conversion process of polysulfides.

Automated summary

The homogeneous CoNiO2/Co4N nanowires supported graphene composite sulfur cathode successfully addressed the shuttle effect of soluble polysulfides and slow reaction kinetics in Li-S batteries, improving both the performance and cycling life of the battery.