Journal
2D MATERIALS
Volume 9, Issue 1, Pages -Publisher
IOP Publishing Ltd
DOI: 10.1088/2053-1583/ac40c5
Keywords
niobium carbide; MXene; porous Nb4N5; heterojunction; lithium-ion battery
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Funding
- National Natural Science Foundation of China [51472186, 52002296]
- State Key Laboratory of Heavy Oil Processing
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Constructing transition metal nitrides (TMNs) with a 2D porous structure is an effective strategy to enhance their electrochemical performance, and in this study, 2D porous Nb4N5@Nb2C heterojunctions were successfully synthesized using a two-step nitridation method in NH3 atmosphere. The heterojunctions showed high rate performance and excellent cycling stability, maintaining 109.2 mAh g(-1) at 2 A g(-1) after 800 cycles, providing a facile strategy for building high-performing 2D porous TMNs and their heterojunctions.
Constructing transition metal nitrides (TMNs) with a 2D porous structure is an effective strategy to alleviate their volume expansion and self-aggregation issues, eventually enhancing their electrochemical performance. However, very few studies have been reported up to now. Herein, 2D porous Nb4N5@Nb2C heterojunctions are successfully synthesized from Nb2C MXene precursor by employing a two-step nitridation method in NH3 atmosphere. Owing to the abundant active sites, fast Li-ions diffusion paths, and sufficient buffer space for releasing volume expansion, 2D porous Nb4N5@Nb2C heterojunctions achieve high rate performance and excellent cycling stability, maintaining 109.2 mAh g(-1) at 2 A g(-1) after 800 cycles. This work provides a facile strategy for building 2D porous TMNs and their heterojunctions with excellent electrochemical performances.
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