4.7 Review

Recent Developments and Advancements in Graphene-Based Technologies for Oil Spill Cleanup and Oil-Water Separation Processes

Journal

NANOMATERIALS
Volume 12, Issue 1, Pages -

Publisher

MDPI
DOI: 10.3390/nano12010087

Keywords

nanomaterials; graphene; water-oil separation; graphene oxide; reduced graphene oxide; foams; sponges; metal meshes

Funding

  1. Qatar University [IRCC-2020-016, NPRP12S-0306-190247]

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The demand for petroleum industry products has led to the development of various separation technologies for oily wastewaters. This review paper focuses on graphene-based technologies for oil spill cleanup and water separation, including membranes, sponges, meshes, hydrogels, aerogels, foam, and coated cotton. These technologies exhibit superhydrophobic/superoleophilic or superhydrophilic/underwater superoleophobic properties, enabling effective oil water separation. The paper also discusses future perspectives on improving the advancements and large-scale applications of oil water separation technologies.
The vast demand for petroleum industry products led to the increased production of oily wastewaters and has led to many possible separation technologies. In addition to production-related oily wastewater, direct oil spills are associated with detrimental effects on the local ecosystems. Accordingly, this review paper aims to tackle the oil spill cleanup issue as well as water separation by providing a wide range of graphene-based technologies. These include graphene-based membranes; graphene sponges; graphene-decorated meshes; graphene hydrogels; graphene aerogels; graphene foam; and graphene-coated cotton. Sponges and aerogels modified by graphene and reduced graphene oxide demonstrated effective oil water separation owing to their superhydrophobic/superoleophilic properties. In addition, oil particles are intercepted while allowing water molecules to penetrate the graphene-oxide-coated metal meshes and membranes thanks to their superhydrophilic/underwater superoleophobic properties. Finally, we offer future perspectives on oil water separation that are hindering the advancements of such technologies and their large-scale applications.

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