Water Uptake in Epoxy Ionic Liquid Free Film Polymer by Gravimetric Analysis and Comparison with Nondestructive Dielectric Analysis

Due to their high surface coverage, good adhesion to metal surfaces, and their excellent corrosion resistance, epoxy thermosets are widely used as protective coatings. However, anticorrosion protection of these coatings can be improved against water uptake and can be tuned by changing the chemical nature of the curing agents. In this work, a comparative study has been performed on the water uptake of an epoxy-amine based on bisphenol A diglycidyl ether (DGEBA) cured with an aliphatic amine and the same epoxy initiated with a phosphonium ionic liquid (IL). Thus, the epoxy networks were immersed in saline water solution in a controlled temperature environment. Gravimetric and electric impedance measurements were carried out for a maximum of 3 months. Results were analyzed in order to assess the water diffusion coefficients and water saturation limits. Two models, the Brasher-Kingsbury and a novel mixing rule, were applied on permittivity values. Results highlighted that epoxy-ionic liquid systems are less sensitive to water uptake than conventional epoxy-amine networks. Due to their higher hydrophobic properties the water diffusion coefficient of epoxy-ionic liquid systems are two times less compared to epoxy-amine samples and the water saturation limit is more than four times less. The analysis also shows that the novel mixing rule model proposed here is prone to better estimate the water uptake with accuracy from electrical impedance measurements.

Automated summary

Epoxy thermosets are widely used as protective coatings due to their high surface coverage and excellent corrosion resistance. This study compares the water uptake of epoxy-amine networks with an aliphatic amine curing agent and epoxy networks initiated with a phosphonium ionic liquid. The results show that epoxy-ionic liquid systems are less sensitive to water uptake and have lower water diffusion coefficients compared to epoxy-amine samples.