Effect of Calcination Conditions on the Properties and Photoactivity of TiO2 Modified with Biuret

A simple wet impregnation-calcination method was used to obtain a series of novel non-metal doped TiO2 photocatalysts. Biuret was applied as C and N source, while raw titanium dioxide derived from sulfate technology process was used as TiO2 and S source. The influence of the modification with biuret and the effect of the atmosphere (air or argon) and temperature (500-800 degrees C) of calcination on the physicochemical properties and photocatalytic activity of the photocatalysts towards ketoprofen decomposition under simulated solar light was investigated. Moreover, selected photocatalysts were applied for ketoprofen photodecomposition under visible and UV irradiation. Crucial features affecting the photocatalytic activity were the anatase to rutile phase ratio, anatase crystallites size and non-metals content. The obtained photocatalysts revealed improved activity in the photocatalytic ketoprofen decomposition compared to the crude TiO2. The best photoactivity under all irradiation types exhibited the photocatalyst calcined in the air atmosphere at 600 degrees C, composed of 96.4% of anatase with 23 nm crystallites, and containing 0.11 wt% of C, 0.05 wt% of N and 0.77 wt% of S.

Automated summary

A series of novel non-metal doped TiO2 photocatalysts were obtained using a simple wet impregnation-calcination method, with crucial factors affecting photocatalytic activity being the anatase to rutile phase ratio, anatase crystallites size, and non-metals content. The photocatalysts exhibited improved activity in ketoprofen decomposition compared to crude TiO2, with the best photoactivity observed in a photocatalyst composed of 96.4% anatase calcined in air at 600 degrees C with specific non-metals content.