Journal
ADVANCED MATERIALS INTERFACES
Volume 9, Issue 7, Pages -Publisher
WILEY
DOI: 10.1002/admi.202101944
Keywords
acid oxygen reduction reaction; anti-sulfate poisoning ability; electrocatalysts; nanostructures; PtZn nanodendrites
Funding
- National Natural Science Foundation of China [21771192]
- Major Program of Shandong Province Natural Science Foundation [ZR2017ZB0315]
- Fundamental Research Funds for the Central Universities [19CX05001A, 18CX02053A]
- Qingdao Applied Basic Research Project [19-6-2-20-cg]
- Yankuang Group 2019 Science and Technology Program [YKKJ2019AJ11JG-R66]
- Taishan Scholar Program of Shandong Province [ts201712019]
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Multidimensional PtZn quasi-cubic nanodendrites with highly active facets and resistance to sulfate were synthesized using a facile oil phase route. The formation mechanism of these nanodendrites and their superior catalytic performance were studied.
The multidimensional PtZn quasi-cubic nanodendrites (PtZn-ND) with tremendous amounts of defectively coarse branches, having both highly active high-index facets and short-range (100) and (110) terraces resisted to sulfate, are synthesized via facile oil phase route at first time. The growth process is found to start from Pt nano-cuboid seeds, then PtZn nanoclovers which are formed from epitaxial growth, and then the flower-like PtZn crystals and finally the novel PtZn-ND. The formation mechanism of PtZn-ND, in particular the effects of hexadecyltrimethyammonium bromide (CTAB) and oleic acid (OA) on the morphology, crystal shape and exposure lattice facets, have been comparatively and systematically studied. And it turns out that CTAB mainly controls depositing directions, while OA mainly controls the crystal shape/size. The combination effect results in unique PtZn-ND structures. The novel PtZn-ND also displays superior catalytic performance and anti-sulfate poisoning ability. In particular, the mass activity (MA) and specific activity (SA) are 5.72 and 7.55 times higher than those of commercial Pt/C, and still 2.91 and 5.09 times higher after accelerated durability tests in 0.5 m H2SO4 for oxygen reduction reaction.
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