Journal
SUSTAINABILITY
Volume 13, Issue 20, Pages -Publisher
MDPI
DOI: 10.3390/su132011386
Keywords
self-healing; crystalline admixtures; chloride diffusion; ultra-high durability concrete
Funding
- European Union's Horizon 2020 research and innovation program [760824]
- COST Action SARCOS [CA 15202]
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Studying the resistance to chloride penetration and the effects of self-healing in cracked concrete structures is crucial. The experimental method involves micro-core drilling at different positions and depths, validated through visual image analysis and crack sealing evaluation.
Chloride diffusion and penetration, and consequently chloride-induced corrosion of reinforcement, are among the most common mechanisms of deterioration of concrete structures, and, as such, the most widely and deeply investigated as well. The benefits of using Ultra-High Performance (Fiber-Reinforced) Concrete-UHP(FR)C to extend the service life of concrete structures in chloride attack scenarios have been addressed, mainly focusing on higher intrinsic durability of the aforementioned category of materials due to their compact microstructure. Scant, if nil, information exists on the chloride diffusion and penetration resistance of UHPC in the cracked state, which would be of the utmost importance, also considering the peculiar (tensile) behavior of the material and its high inborn autogenous healing capacity. On the other hand, studies aimed at quantifying the delay in chloride penetration promoted by self-healing, both autogenous and autonomous, of cracked (ordinary) concrete have started being promoted, further highlighting the need to investigate the multidirectional features of the phenomenon, in the direction both parallel and orthogonal to cracks. In this paper, a tailored experimental methodology is presented and validated to measure, with reference to its multidirectional features, the chloride penetration in cracked UHPC and the effects on it of self-healing, both autogenous and stimulated via crystalline admixtures. The methodology is based on micro-core drilling in different positions and at different depths of UHPC disks cracked in splitting and submitted to different exposure/healing times in a 33 g/L NaCl aqueous solution. Its validation is completed through comparison with visual image analysis of crack sealing on the same specimens as well as with the assessment of crack sealing and of mechanical and permeability healing-induced recovery performed, as previously validated by the authors, on companion specimens.
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