4.6 Review

How Organic Substances Promote the Chemical Oxidative Degradation of Pollutants: A Mini Review

Journal

SUSTAINABILITY
Volume 13, Issue 19, Pages -

Publisher

MDPI
DOI: 10.3390/su131910993

Keywords

organics; chemical; oxidation; Fenton; activated; persulfate; metal-organic framework

Funding

  1. National Key Research and Development Program of China [2018YFC1801100]
  2. National Natural Science Foundation of China [21707041]

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The addition of organic catalysts to promote pollutant oxidation degradation has garnered significant attention. Studies have shown that organic substances can enhance traditional oxidation reactions by accelerating the redox cycle of transition metals, activating oxidants to produce reactive oxygen species, or altering the electron distribution of pollutants. The development of metal-organic frameworks has provided a promising avenue for enhancing practical applications of oxidation technology.
The promotion of pollutant oxidation degradation efficiency by adding organic catalysts has obtained widespread attention in recent years. Studies have shown that organic substances promote the process of traditional oxidation reactions by accelerating the redox cycle of transition metals, chelating transition metals, activating oxidants directly to generate reactive oxygen species such as hydroxyl and sulfate radical, or changing the electron distribution of the target pollutant. Based on the promotion of typical organic functional groups on the chemical oxidative process, a metal-organic framework has been developed and applied in the field of chemical catalytic oxidation. This manuscript reviewed the types, relative merits, and action mechanisms of common organics which promoted oxidation reactions so as to deepen the understanding of chemical oxidation mechanisms and enhance the practical application of oxidation technology.

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