4.6 Article

Study of the Potential Uses of Hydrochar from Grape Pomace and Walnut Shells Generated from Hydrothermal Carbonization as an Alternative for the Revalorization of Agri-Waste in Chile

Journal

SUSTAINABILITY
Volume 13, Issue 22, Pages -

Publisher

MDPI
DOI: 10.3390/su132212600

Keywords

grape pomace; walnut shells; hydrothermal carbonization (HTC); thermogravimetric analysis (TGA); hydrochar

Funding

  1. UNIVERSIDAD DE SANTIAGO DE CHILE through the DICYT ((Direccion de Investigacion Cientifica y Tecnologica) [021812GL]
  2. UNIVERSIDAD DE SANTIAGO DE CHILE [FRAUNHOFER-OC 3134]

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This study aims to explore the potential of using grape pomace and walnut shells treated with hydrothermal carbonization as an alternative low-cost and efficient carbonous matrix. By developing multifunctional carbon materials through thermal decomposition processes, it contributes to increasing the sustainability of biomass applications and has a positive economic impact.
A myriad of resources and efforts have been devoted to assessing the possibilities of using locally sourced biomass to produce energy, reduce CO2 emissions, and, in turn, lower dependance on petroleum. Grape pomace (GP) and walnut shells (WS) are organic waste generated in Chile. Within the last decade, the potential benefits and application of biomass have received significant attention, both in terms of producing functionalized carbon materials, and the various potential applications in the field of energy storage and environmental protection. The proposed research motivation is on the development of carbonous materials through thermal decomposition processes. Few researchers have addressed the idea of developing a multipurpose carbonaceous matrix from hydrochar, and there remains a need for an efficient method to obtain hydrochar specially from grape pomace. Hence, the general objective of this research is to study the potential of grape pomace and walnut shells treated with hydrothermal carbonization (HTC) as an alternative low-cost and efficient carbonous matrix. Proximate and elemental analysis was determined to distinguish the nature of the feedstock along with the hydrochar produced. Yield and reaction severity were also studied to study the impacts of temperature and residence time for both feedstocks. Successful results from the proposed work have broad applications for increasing the sustainability biomass applications, contributing to a positive economic impact.

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