4.8 Article

Diphenylalanine-based degradable piezoelectric nanogenerators enabled by polylactic acid polymer-assisted transfer

Journal

NANO ENERGY
Volume 88, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.nanoen.2021.106229

Keywords

Degradable; Diphenylalanine; Piezoelectric nanogenerator; Polylactic acid; Transfer

Funding

  1. Xidian University
  2. National Natural Science Foundation of China [51973170]
  3. Natural Science Foundation of Shaanxi Province [2019JCW-17, 2020JCW-15]
  4. Fundamental Research Funds for the Central Universities [JC2107, JB211406]
  5. Development and Planning Guide Foundation of Xidian University [21103200005]

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Biocompatible and biodegradable piezoelectric nanogenerator offers a novel energy harvesting approach with high stability and power density, while being able to completely degrade in specific environments, providing an effective solution for powering transient electronics and reducing environmental footprint of devices.
Biocompatible and biodegradable energy harvesters are of significance for biomedical application as an alternative energy source without causing adverse effects to the human body. Intrinsically biocompatible diphenylalanine peptides with good piezoelectric, dielectric, and mechanical properties are promising materials for energy conversion. Herein, we report a degradable piezoelectric nanogenerator (PENG) based on a free-standing polylactic acid film with embedded diphenylalanine microrods arrays. The stiff polylactic acid polymer can remove stiff microrods from rigid silicon substrate and transfer uniformly external forces to them for energy conversion. The PENG produces a maximal output voltage of 1.78 V and a power density of 1.56 W m- 3. Furthermore, the device exhibits full dissolution in alkaline solution, acidic solution and phosphate-buffered saline solution after 25 days at 60 celcius. The degradable PENG provides a viable solution to power transient electronics and reduce the environmental footprint of devices.

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