4.6 Review

Support-based modulation strategies in single-atom catalysts for electrochemical CO2 reduction: graphene and conjugated macrocyclic complexes

Related references

Note: Only part of the references are listed.
Article Chemistry, Physical

Curvature-induced Zn 3d Electron Return on Zn-N4 Single-atom Carbon Nanofibers for Boosting Electroreduction of CO2

Mingwei Fang et al.

Summary: By constructing a Zn single-atom catalyst, high product selectivity and current density were achieved simultaneously at a low overpotential, surpassing previous reports in CO2 reduction efficiency.

CHEMCATCHEM (2021)

Article Engineering, Environmental

Construction of atomically dispersed Cu-N4 sites via engineered coordination environment for high-efficient CO2 electroreduction

Huiyuan Cheng et al.

Summary: Highly exposed atomically dispersed Cu-N-x sites were successfully synthesized through one-step thermal activation, with Cu-N-4 sites exhibiting boosted activity and selectivity by interacting with *COOH intermediate and facilitating desorption of *CO, leading to high CO Faradaic efficiency.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Multidisciplinary

Electroreduction of Carbon Dioxide Driven by the Intrinsic Defects in the Carbon Plane of a Single Fe-N4 Site

Wenpeng Ni et al.

Summary: By coupling with single-atom Fe-N-4 sites, the activity of intrinsic carbon defects can be significantly improved, leading to remarkable enhancements in electrocatalytic performance for CO2 reduction. The resulting catalyst shows high CO Faradaic efficiency, CO selectivity, and current density, demonstrating great potential for the development of rechargeable Zn-CO2 batteries.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Rational Fabrication of Low-Coordinate Single-Atom Ni Electrocatalysts by MOFs for Highly Selective CO2 Reduction

Yan Zhang et al.

Summary: A single-atom Ni catalyst with different N coordination numbers was fabricated using a post-synthetic metal substitution strategy. The Ni-N-3-C catalyst showed significantly enhanced COOH* formation leading to accelerated CO2 reduction, achieving high CO Faradaic efficiency and excellent performance in Zn-CO2 battery. This work provides a new approach for modulation of coordination microenvironment in single-atom catalysts for CO2 utilization.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Dynamic Activation of Adsorbed Intermediates via Axial Traction for the Promoted Electrochemical CO2 Reduction

Xinyue Wang et al.

Summary: An axial traction strategy was developed to optimize the electronic structure of the M-N-4 moiety, leading to atomically dispersed nickel sites coordinated with four nitrogen atoms and one axial oxygen atom embedded within the carbon matrix (Ni-N-4-O/C). This Ni-N-4-O/C electrocatalyst exhibited excellent CO2RR performance with a high CO Faradic efficiency close to 100% at -0.9 V, maintaining the CO FE above 90% in a wide potential window. The superior CO2RR activity is attributed to the axial traction effect induced by the Ni-N-4-O active moiety.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Multidisciplinary

Atomically Dispersed Reactive Centers for Electrocatalytic CO2 Reduction and Water Splitting

Huabin Zhang et al.

Summary: Developing electrocatalytic energy conversion technologies using single-atom catalysts holds great promise in addressing fossil fuel exhaustion and environmental issues. The rational design of coordination and microenvironments significantly impacts the reaction mechanisms and catalytic performance of SACs. Recent advancements in atomically dispersed reactive centers for electrocatalytic CO2 reduction and water splitting show potential for future research and application of SACs in energy conversion.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Identification of Single-Atom Ni Site Active toward Electrochemical CO2 Conversion to CO

Haesol Kim et al.

Summary: The study found that the broken ligand-field symmetry is key for active CO2 electrolysis, which leads to an increase in the Ni redox potential yielding Ni-I, and is directly related to the stability of the Ni center. This suggests a new direction for rational ligand-field engineering of single-atom Ni catalysts for efficient CO2 electrolysis.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Multidisciplinary Sciences

Anomalous collapses of Nares Strait ice arches leads to enhanced export of Arctic sea ice

G. W. K. Moore et al.

Summary: Ice arches at the northern and southern ends of Nares Strait, a key passage in the Arctic, are forming for shorter durations, leading to increased ice transport and accelerating the export of multi-year ice.

NATURE COMMUNICATIONS (2021)

Article Multidisciplinary Sciences

Insights on forming N,O-coordinated Cu single-atom catalysts for electrochemical reduction CO2 to methane

Yanming Cai et al.

Summary: Single-atom catalysts are promising for catalyzing CO2 reduction to produce high value hydrocarbons, but most reactions yield CO. In this study, a low-temperature calcining process was used to fabricate a carbon-dots-based SAC which efficiently converts CO2 to methane.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Multidisciplinary

Atomically Dispersed Indium Sites for Selective CO2 Electroreduction to Formic Acid

Peilong Lu et al.

Summary: A novel atomically dispersed indium catalyst has been developed for efficiently producing formic acid/formate in aqueous media, outperforming conventional metallic In catalysts. The formation of the intermediate *OCHO on isolated In sites plays a pivotal role in the efficiency of the CO2-to-formate process, with a lower energy barrier compared to metallic In.

ACS NANO (2021)

Review Chemistry, Physical

Structure Sensitivity in Single-Atom Catalysis toward CO2 Electroreduction

Dunfeng Gao et al.

Summary: This paper discusses the activity and selectivity of single-atom catalysts (SACs) in the electrocatalytic CO2 reduction reaction (CO2RR) and the influence of structure on these factors, emphasizing the importance of dynamic structural evolution and active sites. The unique role of SACs in tandem CO2RR catalysis is also explored.

ACS ENERGY LETTERS (2021)

Article Chemistry, Physical

Fluorine-tuned single-atom catalysts with dense surface Ni-N4 sites on ultrathin carbon nanosheets for efficient CO2 electroreduction

Shu-Guo Han et al.

Summary: The synthesis of a fluorine-tuned single-atom catalyst with ultrathin nanosheet morphology and high Ni content led to a remarkable electrocatalytic performance for CO2-to-CO conversion. The incorporation of F dopants modulates the electron configuration of active sites, reducing the energy barrier for CO2 activation and promoting the formation of the key *COOH intermediate.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Multidisciplinary

A Unique Gas-Migration, Trapping, and Emitting Strategy for High-Loading Single Atomic Cd Sites for Carbon Dioxide Electroreduction

Shuguang Wang et al.

Summary: In this study, a unique gas-migration, trapping, and emitting strategy was demonstrated for building Cd-based SAC for CO2 reduction. The SAC exhibited high-loading and high efficiency in CO2 reduction process. In situ infrared spectroscopy studies and density functional theory simulations provided insights into the catalytic mechanism of the Cd-based SAC.

NANO LETTERS (2021)

Article Chemistry, Physical

Nonnitrogen Coordination Environment Steering Electrochemical CO2-to-CO Conversion over Single-Atom Tin Catalysts in a Wide Potential Window

Wenpeng Ni et al.

Summary: Replacing Sn-N-4 moieties with a special Sn-C2O2F coordination structure in Sn SAC can efficiently convert CO2 to CO with a Faradaic efficiency up to 95.2%, and theoretical calculations reveal the significant influence of C and O coordination as well as the Sn-bonded F atom on the reaction.

ACS CATALYSIS (2021)

Article Chemistry, Multidisciplinary

Boosting Electrochemical CO2 Reduction by Controlling Coordination Environment in Atomically Dispersed Ni@NxCy Catalysts

Xiao Yang et al.

Summary: Atomically dispersed Ni-based catalysts with various N/C coordination numbers were fabricated, with the Ni@NxCy-1000 catalyst achieving the highest CO selectivity at a specific temperature. Density functional theory calculation revealed that the active Ni-N2C2 sites played a crucial role in enhancing the CO2RR catalytic activity.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Review Multidisciplinary Sciences

Structural tuning of heterogeneous molecular catalysts for electrochemical energy conversion

Jiong Wang et al.

Summary: Heterogeneous molecular catalysts based on transition metal complexes are increasingly being studied for their potential use in electrochemical energy conversion. This review discusses how tuning the first and second coordination spheres of these complexes can optimize their activities and serve as models for studying the impact of structural variations on activity. Structural tuning, such as adjusting ligated atoms and appending adjacent metal centers or pendant groups, can result in different geometric and electronic configurations of the complexes, ultimately leading to improved activity through stability adjustments and redox behaviors.

SCIENCE ADVANCES (2021)

Article Chemistry, Physical

Carbon nanosheets supporting Ni-N3S single-atom sites for efficient electrocatalytic CO2 reduction

Xiaoyi Zhao et al.

Summary: In this study, Ni single atoms coordinated with N and S were successfully prepared for CO2 reduction using a novel method. The resulting porous carbon nanosheets showed high CO selectivity and current density, attributed to their sheet-like morphology and rich N/S-coordinated Ni atoms.

CARBON (2021)

Article Chemistry, Physical

Highly Selective Two-Electron Electrocatalytic CO2 Reduction on Single-Atom Cu Catalysts

Chaochen Xu et al.

Summary: Cu-based electrocatalysts with high catalytic selectivity for the CO2 reduction reaction are a significant technological challenge. A Cu single atom catalyst, Cu-N-4-NG, has been developed for the selective electrocatalytic reduction of CO2 to CO, achieving an 80.6% Faradaic efficiency under moderate applied potential. The single-atom structure and coordination environment, along with moiety-anchoring graphene, contribute to the high selectivity and efficiency of CO production on Cu-N-4-NG compared to bulk Cu catalysts.

SMALL STRUCTURES (2021)

Article Chemistry, Multidisciplinary

Constructing single Cu-N3 sites for CO2 electrochemical reduction over a wide potential range

Jiaqi Feng et al.

Summary: A Cu-N-doped carbon nanotube with an unsaturated coordination Cu atom showed high CO faradaic efficiency in a wide potential range. The theoretical calculations found that the Cu-N-3 site facilitated the formation of COOH*, accelerating the CO2 electrochemical reduction.

GREEN CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Promoting the conversion of CO2 to CH4via synergistic dual active sites

Zhanzhao Fu et al.

Summary: This study introduces a simple coordination regulation method of the active site to improve the efficiency of CO2 conversion, demonstrates the excellent catalytic performance of NiN3B in CH4 conversion, and highlights the synergistic dual active sites formed between non-metal B and metal Ni atoms in catalysis.

NANOSCALE (2021)

Review Chemistry, Multidisciplinary

Two-dimensional matrices confining metal single atoms with enhanced electrochemical reaction kinetics for energy storage applications

Peng Wang et al.

Summary: The review summarizes newly updated synthesis methodologies and structure-activity mechanisms, as well as highlighting cutting-edge applications of SAs@2D hybrids in various rechargeable batteries and the central kinetics amelioration schemes underlying these applications.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Chemistry, Multidisciplinary

N-Bridged Co-N-Ni: new bimetallic sites for promoting electrochemical CO2 reduction

Jiajing Pei et al.

Summary: A highly active CO2RR catalyst, Co-N-Ni/NPCNSs, with N-bridged Co-N-Ni bimetallic sites has been reported. The N-bridged sites were confirmed to promote the formation of COOH* intermediates, thereby accelerating CO2RR. The catalyst showed significantly higher activity and efficiency compared to single Co-N-4 and Ni-N-4 sites.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Electrocatalysis for CO2 conversion: from fundamentals to value-added products

Genxiang Wang et al.

Summary: This article provides a comprehensive review of recent research progress on the selective electrocatalytic conversion of CO2 into value-added products. It covers the history and fundamental science of electrocatalytic CO2RR, the design, preparation, and performance evaluation of electrocatalysts, factors influencing the CO2RR, and associated theoretical calculations. Emphasis is placed on emerging trends in selective electrocatalytic conversion of CO2 and discussions on structure-performance relationships and mechanisms.

CHEMICAL SOCIETY REVIEWS (2021)

Article Chemistry, Physical

Design of bimetallic atomic catalysts for CO2 reduction based on an effective descriptor

Xin Guan et al.

Summary: By extending the descriptor, we were able to study bimetallic atomic catalysts with nitrogen-doped graphene and found an effective way to describe adsorption energies. This allows us to design high-performance catalysts and understand the roles of different dopants in adsorption and reaction.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Physical

Understanding trends in the activity and selectivity of bi-atom catalysts for the electrochemical reduction of carbon dioxide†

Fuhua Li et al.

Summary: Electrocatalytic CO2 reduction is a promising approach for producing valuable chemicals using greenhouse gases, but breaking the traditional scaling relations on conventional transition metal catalysts is crucial to improving efficiency. Recent advances in precise control over the synthesis of biatom catalysts have shown unique catalytic properties different from single-atom catalysts and nanoparticles. While homonuclear BACs still follow scaling relations, heteronuclear BACs can significantly break linear relationships by utilizing different O and C affinities of the heterocenters.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Multidisciplinary

Atomically Defined Undercoordinated Active Sites for Highly Efficient CO2 Electroreduction

Wanzhen Zheng et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Multidisciplinary Sciences

Molecular tuning of CO2-to-ethylene conversion

Fengwang Li et al.

NATURE (2020)

Article Chemistry, Multidisciplinary

Controlled Synthesis of a Vacancy-Defect Single-Atom Catalyst for Boosting CO2 Electroreduction

Xin Rong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Regulating the Coordination Environment of MOF-Templated Single-Atom Nickel Electrocatalysts for Boosting CO2 Reduction

Yun-Nan Gong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Ligand-Controlled Product Selectivity in Electrochemical Carbon Dioxide Reduction Using Manganese Bipyridine Catalysts

Magnus H. Ronne et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

Unveiling the Active Structure of Single Nickel Atom Catalysis: Critical Roles of Charge Capacity and Hydrogen Bonding

Xunhua Zhao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Multidisciplinary Sciences

Renewable electricity storage using electrolysis

Zhifei Yan et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2020)

Article Chemistry, Physical

Activation of Ni Particles into Single Ni-N Atoms for Efficient Electrochemical Reduction of CO2

Qun Fan et al.

ADVANCED ENERGY MATERIALS (2020)

Article Chemistry, Multidisciplinary

Enhanced CO2 Electroreduction on Neighboring Zn/Co Monomers by Electronic Effect

Wenjin Zhu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Chemical Synthesis of Single Atomic Site Catalysts

Shufang Ji et al.

CHEMICAL REVIEWS (2020)

Article Materials Science, Multidisciplinary

Two-electron oxygen reduction reaction by high-loading molybdenum single-atom catalysts

Xuan Zhao et al.

RARE METALS (2020)

Article Chemistry, Multidisciplinary

Well-Defined Single-Atom Cobalt Catalyst for Electrocatalytic Flue Gas CO2 Reduction

Pengfei Hou et al.

SMALL (2020)

Article Chemistry, Physical

Heterogeneous Catalysts with Well-Defined Active Metal Sites toward CO2 Electrocatalytic Reduction

Deren Yang et al.

ADVANCED ENERGY MATERIALS (2020)

Article Chemistry, Physical

Effects of Surface Roughness on the Electrochemical Reduction of CO2 over Cu

Kun Jiang et al.

ACS ENERGY LETTERS (2020)

Article Nanoscience & Nanotechnology

Metal Phthalocyanine-Derived Single-Atom Catalysts for Selective CO2 Electroreduction under High Current Densities

Yang Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Review Chemistry, Multidisciplinary

Heterogeneous Single-Atom Catalysts for Electrochemical CO2Reduction Reaction

Minhan Li et al.

ADVANCED MATERIALS (2020)

Article Chemistry, Multidisciplinary

Axial Modification of Cobalt Complexes on Heterogeneous Surface with Enhanced Electron Transfer for Carbon Dioxide Reduction

Jiong Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Design of a Single-Atom Indiumδ+-N4Interface for Efficient Electroreduction of CO2to Formate

Huishan Shang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Stable and Efficient Single-Atom Zn Catalyst for CO2 Reduction to CH4

Lili Han et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Physical

Fundamentals of Electrochemical CO2 Reduction on Single-Metal-Atom Catalysts

Tu N. Nguyen et al.

ACS CATALYSIS (2020)

Review Chemistry, Physical

Recent Advances in MOF-Derived Single Atom Catalysts for Electrochemical Applications

Zhongxin Song et al.

ADVANCED ENERGY MATERIALS (2020)

Article Multidisciplinary Sciences

A Mn-N3 single-atom catalyst embedded in graphitic carbon nitride for efficient CO2 electroreduction

Jiaqi Feng et al.

NATURE COMMUNICATIONS (2020)

Review Chemistry, Multidisciplinary

Heteroatom-doped carbon catalysts for zinc-air batteries: progress, mechanism, and opportunities

Xiaofeng Zhu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Discovery of main group single Sb-N4 active sites for CO2 electroreduction to formate with high efficiency

Zhuoli Jiang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Review Chemistry, Multidisciplinary

Designing CO2 reduction electrode materials by morphology and interface engineering

Fuping Pan et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Review Chemistry, Multidisciplinary

Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts

Libo Sun et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Breaking scaling relations for efficient CO2 electrochemical reduction through dual-atom catalysts

Yixin Ouyang et al.

CHEMICAL SCIENCE (2020)

Article Chemistry, Physical

Pore size effect of graphyne supports on CO2 electrocatalytic activity of Cu single atoms

Youxuan Ni et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2020)

Article Chemistry, Physical

A CO2 adsorption dominated carbon defect-based electrocatalyst for efficient carbon dioxide reduction

Qilong Wu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Inorganic & Nuclear

Carbon Dioxide Reduction by Iron Hangman Porphyrins

Charles G. Margarit et al.

ORGANOMETALLICS (2019)

Article Chemistry, Multidisciplinary

Covalently Grafting Cobalt Porphyrin onto Carbon Nanotubes for Efficient CO2 Electroreduction

Minghui Zhu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Isolated Diatomic Ni-Fe Metal-Nitrogen Sites for Synergistic Electroreduction of CO2

Wenhao Ren et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Multidisciplinary Sciences

Atomically dispersed Fe3+ sites catalyze efficient CO2 electroreduction to CO

Jun Gu et al.

SCIENCE (2019)

Article Multidisciplinary Sciences

Molecular electrocatalysts can mediate fast, selective CO2 reduction in a flow cell

Shaoxuan Ren et al.

SCIENCE (2019)

Article Chemistry, Physical

Phthalocyanine Precursors To Construct Atomically Dispersed Iron Electrocatalysts

Yang Wang et al.

ACS CATALYSIS (2019)

Article Chemistry, Physical

Electrochemical Reduction of CO2 on Metal-Nitrogen-Doped Carbon Catalysts

Ana Sofia Varela et al.

ACS CATALYSIS (2019)

Article Chemistry, Physical

Cobalt phthalocyanine coordinated to pyridine-functionalized carbon nanotubes with enhanced CO2 electroreduction

Minghui Zhu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

Article Chemistry, Multidisciplinary

Scalable Production of Efficient Single-Atom Copper Decorated Carbon Membranes for CO2 Electroreduction to Methanol

Hengpan Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Physical

Dynamic charge and oxidation state of Pt/CeO2 single-atom catalysts

Nathan Daelman et al.

NATURE MATERIALS (2019)

Article Multidisciplinary Sciences

Domino electroreduction of CO2 to methanol on a molecular catalyst

Yueshen Wu et al.

NATURE (2019)

Article Chemistry, Multidisciplinary

Atomic Ni Anchored Covalent Triazine Framework as High Efficient Electrocatalyst for Carbon Dioxide Conversion

Chenbao Lu et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Article Multidisciplinary Sciences

Double-slit photoelectron interference in strong-field ionization of the neon dimer

Maksim Kunitski et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Physical

Challenges in Modeling Electrochemical Reaction Energetics with Polarizable Continuum Models

Joseph A. Gauthier et al.

ACS CATALYSIS (2019)

Article Chemistry, Multidisciplinary

Efficient and Robust Carbon Dioxide Electroreduction Enabled by Atomically Dispersed Snδ+ Sites

Xiaolong Zu et al.

ADVANCED MATERIALS (2019)

Article Chemistry, Multidisciplinary

Intrinsic Carbon-Defect-Driven Electrocatalytic Reduction of Carbon Dioxide

Wei Wang et al.

ADVANCED MATERIALS (2019)

Review Chemistry, Multidisciplinary

Surface strategies for catalytic CO2 reduction: from two-dimensional materials to nanoclusters to single atoms

Liming Wang et al.

CHEMICAL SOCIETY REVIEWS (2019)

Article Chemistry, Physical

Electrochemical reduction of CO2 by single atom catalyst TM-TCNQ monolayers

Jin-Hang Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Article Chemistry, Multidisciplinary

Efficient CO2 to CO electrolysis on solid Ni-N-C catalysts at industrial current densities

Tim Moeller et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

Review Chemistry, Inorganic & Nuclear

Nitrogen-doped metal-free carbon catalysts for (electro)chemical CO2 conversion and valorisation

Diana M. Fernandes et al.

DALTON TRANSACTIONS (2019)

Article Chemistry, Multidisciplinary

An Integrated Design with new Metal-Functionalized Covalent Organic Frameworks for the Effective Electroreduction of CO2

Cang-Lang Yao et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Article Chemistry, Multidisciplinary

Coordinatively unsaturated nickel-nitrogen sites towards selective and high-rate CO2 electroreduction

Chengcheng Yan et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Article Chemistry, Multidisciplinary

Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction

Kun Jiang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Article Chemistry, Physical

The role of reticular chemistry in the design of CO2 reduction catalysts

Christian S. Diercks et al.

NATURE MATERIALS (2018)

Article Energy & Fuels

Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction

Hong Bin Yang et al.

NATURE ENERGY (2018)

Review Chemistry, Multidisciplinary

Heterogeneous single-atom catalysis

Aiqin Wang et al.

NATURE REVIEWS CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

Highly Efficient CO2 Electroreduction on ZnN4-based Single-Atom Catalyst

Fa Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

Reaction Mechanisms of Well-Defined Metal-N-4 Sites in Electrocatalytic CO2 Reduction

Zheng Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Editorial Material Multidisciplinary Sciences

The irreversible momentum of clean energy

Barack Obama

SCIENCE (2017)

Article Chemistry, Multidisciplinary

Single-atom catalysts for CO2 electroreduction with significant activity and selectivity improvements

Seoin Back et al.

CHEMICAL SCIENCE (2017)

Article Multidisciplinary Sciences

In situ click chemistry generation of cyclooxygenase-2 inhibitors

Atul Bhardwaj et al.

NATURE COMMUNICATIONS (2017)

Article Chemistry, Multidisciplinary

Reversible Transformation of Pt Nanoparticles into Single Atoms inside High-Silica Chabazite Zeolite

Manuel Moliner et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Multidisciplinary

Electrochemical CO2 Reduction to Hydrocarbons on a Heterogeneous Molecular Cu Catalyst in Aqueous Solution

Zhe Weng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Multidisciplinary

Efficient electrocatalytic CO2 reduction with a molecular cofacial iron porphyrin dimer

Eman A. Mohamed et al.

CHEMICAL COMMUNICATIONS (2015)

Article Chemistry, Physical

Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide

Ruud Kortlever et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2015)

Article Multidisciplinary Sciences

Efficient and selective molecular catalyst for the CO2-to-CO electrochemical conversion in water

Cyrille Costentin et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2015)

Review Chemistry, Multidisciplinary

Ligand design for functional metal-organic frameworks

Filipe A. Almeida Paz et al.

CHEMICAL SOCIETY REVIEWS (2012)

Review Chemistry, Multidisciplinary

Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal centre of CO2 reduction catalysts

Jacob Schneider et al.

CHEMICAL SOCIETY REVIEWS (2012)

Review Multidisciplinary Sciences

Opportunities and challenges for a sustainable energy future

Steven Chu et al.

NATURE (2012)

Review Chemistry, Inorganic & Nuclear

Bioinorganic chemistry of molybdenum and tungsten enzymes: A structural-functional modeling approach

Amit Majumdar et al.

COORDINATION CHEMISTRY REVIEWS (2011)

Article Chemistry, Multidisciplinary

Single-atom catalysis of CO oxidation using Pt1/FeOx

Botao Qiao et al.

NATURE CHEMISTRY (2011)

Editorial Material Chemistry, Multidisciplinary

Introduction:: Molecular and biomolecular electrochemistry

Jean-Michel Saveant

CHEMICAL REVIEWS (2008)

Article Multidisciplinary Sciences

Simulation of the folding equilibrium of α-helical peptides:: A comparison of the generalized born approximation with explicit solvent

H Nymeyer et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2003)

Article Biochemistry & Molecular Biology

Evaluation of a fast implicit solvent model for molecular dynamics simulations

P Ferrara et al.

PROTEINS-STRUCTURE FUNCTION AND BIOINFORMATICS (2002)