4.6 Article

Advanced metal oxide infiltrated electrodes for boosting the performance of solid oxide cells

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 10, Issue 5, Pages 2541-2549

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ta07902f

Keywords

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Funding

  1. ERDF A way of making Europe
  2. Ramon y Cajal program [MCIN/AEI/10.13039/501100011033, RYC2018-025553-I]
  3. ESF Investing in your future
  4. [PID2019-107106RB-C32]
  5. [RTI2018-098944-J-I00]

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The study focuses on enhancing the performance of oxygen electrodes by infiltrating metal oxide nanoparticles. Different metal oxides such as cerium oxide, praseodymium or manganese oxide will be examined for their effect on the performance of lanthanum strontium manganite oxygen electrodes. The infiltration of metal oxides significantly improves the current densities in both fuel cell and electrolysis modes in comparison with literature results for microtubular configuration.
An efficient way for boosting the performance of solid oxide electrodes is the infiltration of metallic nanoparticles into both electrodes. In this work we will focus on improving the performance of standard lanthanum strontium manganite oxygen electrodes, by the addition of different metal oxide nanoparticles. First studies will be performed using cerium oxide nanoparticles, as this is the classic oxide already proposed in the literature. Other novel metal oxides such as praseodymium or manganese oxide will be explored, as studies in the literature for these two metal oxides are very scarce. The effect of metal oxide infiltration into LSM/YSZ oxygen electrodes will be studied in both symmetrical cells and complete microtubular cells using conventional fuel electrodes (NiO-YSZ) and electrolytes (YSZ). The obtained current densities in both fuel cell and electrolysis modes are significantly enhanced in comparison with other results in the literature for microtubular configuration.

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