Journal
IEEE JOURNAL OF PHOTOVOLTAICS
Volume 12, Issue 1, Pages 316-321Publisher
IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC
DOI: 10.1109/JPHOTOV.2021.3114597
Keywords
Absorption; Photovoltaic systems; Morphology; Excitons; Electrodes; Photovoltaic cells; Polymers; All-small-molecule solar cells; complementary absorption; nonfullerene acceptors (NFAs); short-circuit current density
Funding
- National Key Research and Development Program of China [2017YFA0206602]
- National Natural Science Foundation of China [51773065, 51861145301]
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This study emphasizes the importance of minimizing the absorption overlap between the donor and acceptor in all-small-molecule organic solar cells for achieving high current densities. By selecting porphyrin unit-based small molecules with absorption ranges different from the nonfullerene acceptor IDIC, it is possible to enhance the power conversion efficiency of the devices.
It is crucial to minimize the absorption overlap between donor and acceptor for high-efficiency all-small-molecule organic solar cells with high current densities. Considering strong absorption of nonfullerene acceptors 2,2.-((2Z,2?Z)-((4,4,9,9-tetrahexyl-4,9-dihydro-s-indaceno[1,2-b:5,6-b.]dithiophene-2,7-diyl)bis(methanylylidene))bis(3-oxo-2,3-dihydro-1H-indene-2,1-diylidene))dimalononitrile (IDIC) in the ranges of 650-750 nm, two porphyrin unit-based small molecules containing diketopyrrolopyrrole groups (Dipor and Por) are selected as the electron donor materials because of their weak absorption in this region. Porphyrin dimer Dipor displays a broad photon response from 300 to 1000 nm in the films and its absorption deficiency between the Soret and Q-bands could be perfectly compensated by nonfullerene acceptors IDIC, while monomer Por shows partial overlapping absorption to IDIC in ranges of 650-700 nm and its absorption edge locates at similar to 900 nm. The higher compatibility of porphyrin dimer Dipor and IDIC results in a promising power conversion efficiency of 8.3% with a high short-circuit current density (Jsc) of 20.2 mA cm-2, whereas the devices based on Por: IDIC show a lower power conversion efficiency of 6.3%.
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