Durable antibacterial and UV protections of in situ synthesized zinc oxide nanoparticles onto cotton fabrics

Herein we represent a new discovery based on amine material called hexamethyltriethylene tetramine (HMTETA). We have observed that when an aqueous solution of Zn(NO3).6H(2)O was added to aqueous solution of HMTETA followed by shaking for a time, the colorless solution was converted to milky color under the alkaline medium provided by HMTETA prior to formation of uniform zinc oxide nanoparticles (ZnO NPs). The latter are in situ formed within the cotton fabrics without the support of capping or other stabilizing agents. Obviously, then, the new made of formation of ZnO NPs speaks of a single-stage process where cotton fabric is immersed in a prepared solution of the new precursors through which binding of ZnO NPs into the textile fabrics takes place. Textile fabrics are, indeed, used as a template, which is capable of maintaining the size and surface distribution of the as-synthesized nanoparticles in a uniform domain. It is also likely that nanoparticles is confined inside the fibril and microfibrils of the cotton fibers. World-class facilities have been employed to follow up the synthesis of ZnO NPs, their characterization and their application to confer, in particular, high durable antibacterial and UV protective function on cotton fabrics. (C) 2015 Elsevier B.V. All rights reserved.