Journal
POLYMERS
Volume 14, Issue 4, Pages -Publisher
MDPI
DOI: 10.3390/polym14040659
Keywords
silk filaments; fibroin; sericin; green degumming; enzyme; evaluation; properties
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Silk, composed of fibroin and sericin, requires separation before further processing due to their significant differences. The traditional degumming processes may cause environmental damage and harm to silk fibroin, thus the research and selection of environmentally friendly degumming processes are crucial for both textile and non-textile applications.
Silk has been widely used not only in the textile field but also in non-textile applications, which is composed of inner fibrous protein, named fibroin, and outer global protein, named sericin. Due to big differences, such as appearance, solubility, amino acid composition and amount of reactive groups, silk fibroin and sericin usually need to be separated before further process. The residual sericin may influence the molecular weight, structure, morphology and properties of silk fibroin, so that degumming of silk is important and necessary, not only in textile field but also in non-textile applications. Traditional textile degumming processes, including soap, alkali or both, could bring such problems as environmental damage, heavy use of water and energy, and damage to silk fibroin. Therefore, this review aims to present a systematic work on environmentally friendly and green degumming processes of raw silk, including art of green degumming process, quantitative and qualitative evaluation, influence of degumming on molecular weight, structure, morphology and properties of silk. It is anticipated that rational selection and design of environmentally friendly and green degumming process is quite important and meaningful, not only for textile application but also for non-textile application.
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