Journal
SCIENTIFIC REPORTS
Volume 11, Issue 1, Pages -Publisher
NATURE PORTFOLIO
DOI: 10.1038/s41598-021-04111-z
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Funding
- Iranian National Science Foundation (INSF) [97017223]
- Ilam University
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A novel magnetic nanocatalyst was successfully synthesized and characterized for its catalytic activity in Suzuki and Stille coupling reactions. This catalyst can be easily separated and reused due to its magnetic properties, maintaining high catalytic activity.
In this research, natural asphalt as a mineral carbonuous material was converted to sodium natural asphalt sulfonate (Na-NAS) and, then, was linked to Fe3O4 MNPs in order to synthesize the magnetic nanocatalyst. Afterwards, Cupper (I) and Cu (II) was grafted on Fe3O4-PTMS-NAS. Moreover, it is worth mentioning that the synthesized the novel magnetic nanocatalyst (Fe3O4-PTMS-NAS@Cu) was successfully used in Suzuki and Stille coupling reactions. The Fe3O4-PTMS-NAS@Cu MNPs were characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), thermogravimetric analysis (TGA), vibrating sample magnetometry (VSM), inductively coupled plasma (ICP), BET and X-ray photoelectron spectroscopy (XPS) analysis. Besides, sulfonation of natural asphalt, magnetization of catalyst, grafting of Cu (I) and Cu (II) to NAS and catalyst formation were investigated and proved carefully. This nanocatalyst can be comfortably separated from the reaction medium through an external magnetic field and can also be recovered and reused, while maintaining its catalytic activity.
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