Development of dual-functional catalysis for hydrazine oxidation by an organic p-n bilayer through in situ formation of a silver co-catalyst

Dual-functional catalysis indicates that an organic p-n bilayer induces the catalytic oxidation involved in downhill reactions, not only under illumination but also in the dark. When the organo-bilayer is composed of a perylene derivative (3,4,9,10-perylenetetracarboxylic-bis-benzimidazole (PTCBI), n-type) and cobalt phthalocyanine (CoPc, p-type), only the photocatalytic oxidation of hydrazine (N2H4) occurs. However, the loading of Ag co-catalyst onto the CoPc surface in the PTCBI/CoPc bilayer successfully led to dual catalysis in terms of the oxidation of N2H4 to N-2. To develop the present dual catalysis Ag loading was essential to achieve the catalysis performance particularly without irradiation.

Automated summary

Dual-functional catalysis refers to the induction of catalytic oxidation in both illuminated and dark conditions by an organic p-n bilayer. Loading Ag co-catalyst onto the bilayer surface enables dual catalysis, particularly without irradiation.