Journal
RSC ADVANCES
Volume 12, Issue 3, Pages 1850-1854Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ra07960c
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Funding
- JSPS KAKENHI [JP18K05287]
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Dual-functional catalysis refers to the induction of catalytic oxidation in both illuminated and dark conditions by an organic p-n bilayer. Loading Ag co-catalyst onto the bilayer surface enables dual catalysis, particularly without irradiation.
Dual-functional catalysis indicates that an organic p-n bilayer induces the catalytic oxidation involved in downhill reactions, not only under illumination but also in the dark. When the organo-bilayer is composed of a perylene derivative (3,4,9,10-perylenetetracarboxylic-bis-benzimidazole (PTCBI), n-type) and cobalt phthalocyanine (CoPc, p-type), only the photocatalytic oxidation of hydrazine (N2H4) occurs. However, the loading of Ag co-catalyst onto the CoPc surface in the PTCBI/CoPc bilayer successfully led to dual catalysis in terms of the oxidation of N2H4 to N-2. To develop the present dual catalysis Ag loading was essential to achieve the catalysis performance particularly without irradiation.
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