Unravelling the one-pot conversion of biomass-derived furfural and levulinic acid to 1,4-pentanediol catalysed by supported RANEY® Ni-Sn alloy catalysts

Bimetallic Ni-Sn alloys have been recognised as promising catalysts for the transformation of furanic compounds and their derivatives into valuable chemicals. Herein, we report the utilisation of a supported bimetallic RANEY (R) nickel-tin alloy supported on aluminium hydroxide (RNi-Sn(x)/AlOH; x is Ni/Sn molar ratio) catalysts for the one-pot conversion of biomass-derived furfural and levulinic acid to 1,4-pentanediol (1,4-PeD). The as prepared RNi-Sn(1.4)/AlOH catalyst exhibited the highest yield of 1,4-PeD (78%). The reduction of RNi-Sn(x)/AlOH with H-2 at 673-873 K for 1.5 h resulted in the formation of Ni-Sn alloy phases (e.g., Ni3Sn and Ni3Sn2) and caused the transformation of aluminium hydroxide (AlOH) to amorphous alumina (AA). The RNi-Sn(1.4)/AA 673 K/H-2 catalyst contained a Ni3Sn2 alloy as the major phase, which exhibited the best yield of 1,4-PeD from furfural (87%) at 433 K, H-2 3.0 MPa for 12 h and from levulinic acid (up to 90%) at 503 K, H-2 4.0 MPa, for 12 h. Supported RANEY (R) Ni-Sn(1.5)/AC and three types of supported Ni-Sn(1.5) alloy (e.g., Ni-Sn(1.5)/AC, Ni-Sn(1.5)/c-AlOH, and Ni-Sn(1.5)/gamma-Al2O3) catalysts afforded high yields of 1,4-PeD (65-87%) both from furfural and levulinic acid under the optimised reaction conditions.

Automated summary

Bimetallic nickel-tin alloys supported on aluminum hydroxide have been successfully utilized as catalysts for the conversion of furfural and levulinic acid into 1,4-pentanediol. The prepared RNi-Sn(1.4)/AlOH catalyst showed the highest yield of 1,4-PeD (78%). Reduction of the catalyst with H-2 resulted in the formation of Ni-Sn alloy phases and the transformation of aluminum hydroxide to amorphous alumina, leading to increased yields of the desired product.