4.6 Article

A Novel Graphite-Based Sorbent for Oil Spill Cleanup

Journal

MATERIALS
Volume 15, Issue 2, Pages -

Publisher

MDPI
DOI: 10.3390/ma15020609

Keywords

water remediation; hydrocarbons removal; selective adsorption; innovative adsorbents; super-expanded graphite; sustainable remediation

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The performance of an innovative material Grafysorber(R) G+ was tested for oil removal and water treatment. The material showed high adsorption capacity and can be reused after regeneration. Compared to polypropylene flakes, Grafysorber(R) G+ has economic advantages.
The performance of an innovative material based on expanded graphite, Grafysorber(R) G+ (Directa Plus), has been tested through laboratory, tank, and confinement tests for oil removal in case of an oil spill and water treatment. In addition to the ability to retain oil, the possibility of reusing this material after regeneration via squeezing was also evaluated. As a comparison, the same experimental tests were conducted using polypropylene flakes (PP), the material currently most used to deal with spill accidents. Oils with different chemical and physical properties were used, namely kerosene, diesel, and crude oil. From the laboratory tests, the capacity of Grafysorber(R) G+ to retain oil was found to be directly proportional to the viscosity of the latter, with adsorption values ranging from 76.8 g/g for diesel to 50.8 g/g for kerosene, confirming the potential of the innovative material compared to the PP. Cyclical use tests have confirmed certain reusability of the material, even if its adsorbent capacity decreases significantly after the first cycle and continues to decrease in subsequent cycles, but a less marked manner. Finally, some considerations based on the adsorption capacities were found to suggest that the adoption of the new material is also economically preferable, resulting in savings of 20 to 40% per kg of hydrocarbon treated.

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