4.6 Article

FeZrN Films: Magnetic and Mechanical Properties Relative to the Phase-Structural State

Journal

MATERIALS
Volume 15, Issue 1, Pages -

Publisher

MDPI
DOI: 10.3390/ma15010137

Keywords

Fe-based films; magnetron sputtering; nanocrystalline; phase composition; transmission electron microscopy; X-ray diffraction; nanoindentation; magnetic properties

Funding

  1. Ministry of Science and Higher Education within FSRC Crystallography and Photonics RAS [AAAA-A20-12-0022890089-5]
  2. Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences [075-00328-21-00]

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This paper investigates the influence of the chemical and phase compositions and structure of Fe65.3-100Zr34.7-0N7.5-0 films prepared by dc magnetron deposition on glass substrates and subsequent annealing on their mechanical and magnetic properties. The results show that these films exhibit high hardness, low elastic modulus, good elastic recovery, high saturation induction, and low coercive field.
The paper presents results of investigation of Fe65.3-100Zr34.7-0N7.5-0 films prepared by dc magnetron deposition on glass substrates and subsequent 1-hour annealing at temperatures of 300-600 degrees C. The influence of the chemical and phase compositions and structure of the films, which were studied by TEM, SEM, XRD, and GDOES, on their mechanical properties determined by nanoindentation and static magnetic properties measured by VSM method is analyzed. The studied films exhibit the hardness within a range of 14-21 GPa, low elastic modulus (the value can reach 156 Gpa), and an elastic recovery of 55-83%. It was shown that the films are strong ferromagnets with the high saturation induction Bs (up to 2.1 T) and low coercive field Hc (as low as 40 A/m). The correlations between the magnetic and mechanical properties, on one hand, and the chemical composition of the films, their phase, and structural states as well, on the other hand, are discussed.

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