The effect of four methods of surface activation for improved adhesion of wood polymer composites (WPCs)

Wood Polymer Composites (WPCs) have attracted a lot of interest in recent years as materials with a high renewable content. However the adhesion between WPC components is problematic because of low surface energy and the hydrophobic nature of the most widely used polymer matrices, i.e. polyolefins. Thus this paper has looked at four surface activation pretreatment methods to improve adhesion properties for bonding using epoxy adhesives, namely: hydrogen peroxide solution; hot air; a gas flame; and halogen heating lamps. The treatments were applied to WPC materials made from 60% wood flour in a polypropylene matrix, and lap joint shear strength was measured. Shear strength values showed that all treatments except the halogen heating lamps increased the bond strength and the best results were achieved with hydrogen peroxide treatment at a pH of 7.5 (37% improvement); a two pass hot air treatment at a pass speed of 75 mm s(-1) (44% improvement); and a gas flame treatment at a pass speed of 175 mm s(-1)(41% improvement).The bond strength was increased to values that caused failure within the material, rather than at the interfaces of the bond line. (C) 2016 Elsevier Ltd. All rights reserved.