Journal
ADVANCED ENERGY MATERIALS
Volume 11, Issue 42, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202102169
Keywords
ambient air processing; efficiency; non-halide engineering; perovskite solar cells; stability
Categories
Funding
- National Natural Science Foundation of China [61974106]
- Fundamental Research Funds for the Central Universities [2042020kf0195]
Ask authors/readers for more resources
The study introduces a novel precursor engineering method for fabricating high-efficiency perovskite solar cells using non-halide lead sources in ambient air, demonstrating both stability and high efficiency in humid conditions.
The realization of highly efficient perovskite solar cells (PSCs) in ambient air is considered to be advantageous for low-cost commercial manufacturing. However, it is fundamentally difficult to achieve comparable device performance to that obtained in an inert atmosphere, especially when the ambient humidity is high. Here, an effective precursor engineering that simultaneously employs non-halide lead acetate and lead thiocyanate lead sources for fabricating high-quality methylammonium lead iodide perovskite films in ambient air with enhanced moisture tolerance, is reported. The presence of Ac- and SCN- ions not only enables the facile formation of homogeneous and highly crystalized perovskite films, but also directs the uniform growth of the crystals along the (110) direction. Accordingly, a 20.55% efficiency is demonstrated, one of the best results for air-processed MAPbI(3) PSCs, which is also the highest value achieved with non-halide lead sources. Furthermore, the unencapsulated device shows fivefold prolonged air stability (3600 h) compared to the conventional PbI2-based PSC. Together with the use of non-toxic antisolvent, this strategy is fully compatible with ambient air operation and thus of great potential for practical applications.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available