4.6 Article

Microstructural Characteristics and Mechanical Properties of Cast Mg-3Nd-3Gd-xZn-0.5Zr Alloys

Journal

ACTA METALLURGICA SINICA-ENGLISH LETTERS
Volume 35, Issue 6, Pages 922-940

Publisher

CHINESE ACAD SCIENCES, INST METAL RESEARCH
DOI: 10.1007/s40195-021-01315-0

Keywords

Mg-Nd-Gd alloy; Zn addition; Competitive precipitation behavior; Microstructural characterization

Funding

  1. National Natural Science Foundation of China [U2037601, 51775334, 51821001]
  2. National Key Research & Development Program of China [2016YFB0701205]
  3. Joint Innovation Fund of CALT and College [CALT2020-TS07]
  4. Open Fund of State Key Laboratory of Advanced Forming Technology and Equipment [SKL2020005]
  5. Research Program of Joint Research Center of Advanced Spaceflight Technologies [USCAST2020-14]

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The microstructure, aging behavior, and mechanical properties of cast Mg-3Nd-3Gd-xZn-0.5Zr (x = 0, 0.5, 0.8, 1 wt%) alloys were investigated. The addition of Zn led to the formation of Zn-Zr particles with different morphologies during solution treatment, influencing the precipitation behavior and subsequently the mechanical properties of the alloys. The best tensile properties were achieved in the alloy with 0.5 wt% Zn addition, with a yield strength of 179 MPa, ultimate tensile strength of 301 MPa, and elongation of 5.3% in peak-aged conditions.
The microstructure, aging behavior and mechanical properties of cast Mg-3Nd-3Gd-xZn-0.5Zr (x = 0, 0.5, 0.8, 1 wt%) alloys are investigated in this work. Zn-Zr particles with different morphologies form during solution treatment due to the additions of Zn. As the Zn content increases, the number density of Zn-Zr particles also increases. Microstructural comparisons of peak-aged studied alloys indicate that varying Zn additions could profoundly influence the competitive precipitation behavior. In the peak-aged Zn-free alloy, beta '' phases are the key strengthening precipitates. When 0.5 wt% Zn is added, besides beta '' precipitates, additional fine beta(1) precipitates form. With the addition of 0.8 wt% Zn, the peak-aged 0.8Zn alloy is characterized by predominantly prismatic beta(1) and scanty basal precipitate distributions. The enhanced precipitation of beta(1) should be primarily attributable to the presence of increased Zn-Zr dispersoids. When Zn content further increases to 1 wt%, the precipitation of basal precipitates is markedly enhanced. Basal precipitates and beta(1) phases are the key strengthening precipitates in the peak-aged 1Zn alloy. Tensile tests reveal that the relatively best tensile properties are achieved in the peak-aged alloy with 0.5 wt% Zn addition, whose yield strength, ultimate tensile strength and elongation are 179 MPa, 301 MPa and 5.3%, respectively.

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