Journal
NATURE COMMUNICATIONS
Volume 12, Issue 1, Pages -Publisher
NATURE PORTFOLIO
DOI: 10.1038/s41467-021-26265-0
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Funding
- National Key Research and Development Program of China [2019YFA0704900]
- Natural Science Foundation of China [51632006, 51521001, 52072282]
- 111 Project of China [B07040]
- Fundamental Research Funds for the Central Universities [WUT: 2020IVA097, WUT: 2021III016GX]
- Hubei Post-doctoral Innovation Research Post Fund (second batch)
- NSF [DMR 1307740]
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Researchers have successfully synthesized beta-Zn4Sb3 with improved stability and extended temperature range using an electric field-assisted method, and found that the mobile ions play a crucial role in enhancing the thermoelectric performance of the material.
beta-Zn4Sb3 has promising thermoelectric performance, but its ionic migration properties make it prone to degradation. Here the authors exploit the ion migration in an electric field-assisted synthesis method, fast producing beta-Zn4Sb3 with improved phase stability and extended temperature range for the thermoelectric operation. Mobile ion-enabled phenomena make beta-Zn4Sb3 a promising material in terms of the re-entry phase instability behavior, mixed electronic ionic conduction, and thermoelectric performance. Here, we utilize the fast Zn2+ migration under a sawtooth waveform electric field and a dynamical growth of 3-dimensional ionic conduction network to achieve ultra-fast synthesis of beta-Zn4Sb3. Moreover, the interplay between the mobile ions, electric field, and temperature field gives rise to exquisite core-shell crystalline-amorphous microstructures that self-adaptively stabilize beta-Zn4Sb3. Doping Cd or Ge on the Zn site as steric hindrance further stabilizes beta-Zn4Sb3 by restricting long-range Zn2+ migration and extends the operation temperature range of high thermoelectric performance. These results provide insight into the development of mixed-conduction thermoelectric materials, batteries, and other functional materials.
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