Preparation and characterization of an electromagnetic composite polypyrrole/polyethylene short filament geotextile

In this paper, firstly, polypyrrole was prepared by in situ polymerization using pyrrole as the monomer, hexahydrate ferric chloride as the oxidizer and dopant, and polyethylene geotextile as the substrate to prepare a polypyrrole/polyethylene short filament geotextile composite; secondly, the electromagnetic microwave absorption property and shielding property of the polypyrrole/polyethylene short filament geotextile composite were investigated; finally, the chemical structure of the polypyrrole/polyethylene short filament geotextile composite was characterized by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), X-ray diffraction (XRD), and Raman test methods. The results show that the reflection loss value is up to the minimum value of -17.53 dB in the frequency range of 0-3 GHz and the best absorbing performance is obtained at the frequency of 1.12 GHz. In the frequency range of 0.95-1.25 GHz, the reflection loss value is less than -10 dB, and the electromagnetic wave is effectively absorbed. The shielding effectiveness value is up to the maximum value of 16.07 dB at the frequency of 1.19 GHz, that is, the shielding ability becomes strongest at the frequency of 1.19 GHz; otherwise, the shielding effectiveness is higher than 14 dB in the frequency range of 0.17-3.0 GHz. The FTIR, Raman, XRD, and DSC tests result show that polypyrrole has been successfully loaded on the polyethylene geotextile, improving the crystallinity and thermal stability property of the composite.

Automated summary

This study prepared a polypyrrole/polyethylene short filament geotextile composite using in situ polymerization and investigated its electromagnetic microwave absorption and shielding properties. The results showed that the composite exhibited excellent absorption and shielding performance in specific frequency ranges, with the loaded polypyrrole enhancing the properties of the polyethylene geotextile.