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ORGANIC LETTERS (2018)
Enantioselective Bromocyclization of Allylic Amides Mediated by Phosphorus Catalysis
Yuji Kawato et al.
SYNLETT (2018)
Enantioselective Synthesis of F-Ring Fragments of Kibdelone C via Desymmetrizing Bromolactonization of 1,4-Dihydrobenzoic Acid
Daniel W. Klosowski et al.
SYNLETT (2018)
Enantioselective Construction of Bridgehead Quaternary Carbon Containing Bicyclo[3.3.1]nonanes by Palladium-Catalyzed Desymmetric Arylation
Jinhui Cai et al.
SYNTHESIS-STUTTGART (2018)
Recent examples of the use of biocatalysts with high accessibility and availability in natural product synthesis
Takeshi Sugai et al.
TETRAHEDRON (2018)
Total synthesis of natural products using a desymmetrization strategy
Makoto Inai et al.
TETRAHEDRON LETTERS (2018)
Diastereo- and enantioselective copper catalyzed hydroallylation of disubstituted cyclopropenes
Heiko Sommer et al.
CHEMICAL SCIENCE (2018)
Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation
Jie Luo et al.
NATURE COMMUNICATIONS (2018)
Asymmetric C(sp)-H Addition of Terminal Alkynes to Cyclopropenes by a Chiral Gadolinium Catalyst
Huai-Long Teng et al.
ACS CATALYSIS (2018)
Desymmetrizing Enantio- and Diastereoselective Selenoetherification through Supramolecular Catalysis
Jie Yang See et al.
ACS CATALYSIS (2018)
Catalytic approaches to assemble cyclobutane motifs in natural product synthesis
Meng Wang et al.
ORGANIC CHEMISTRY FRONTIERS (2018)
N-Heterocyclic carbene promoted enantioselective desymmetrization reaction of diarylalkane-bisphenols
Shoulei Li et al.
ORGANIC CHEMISTRY FRONTIERS (2018)
Highly enantioselective desymmetrization of prochiral cyclic α,α-dicyanoalkenes via the direct vinylogous Michael/cyclization domino reaction
Hongjiang Mei et al.
ORGANIC CHEMISTRY FRONTIERS (2018)
Non-Covalent Substrate Directed Enantioselective Heck Desymmetrization of cis-Cyclohex-4-ene-1,2-diol: Synthesis of all cis Chiral 5-Aryl-cyclohex-3-ene-1,2-diols and Mechanistic Investigation
Ricardo A. Angnes et al.
ADVANCED SYNTHESIS & CATALYSIS (2018)
Enzymatic Desymmetrization of 19-nor-Vitamin D3 A-Ring Synthon Precursor: Synthesis, Structure Elucidation, and Biological Activity of 1α,25-Dihydroxy-3-epi-19-nor-vitamin D3 and 1β,25-Dihydroxy-19-nor-vitamin D3
Tania Gonzalez-Garcia et al.
ADVANCED SYNTHESIS & CATALYSIS (2018)
Diversiform Reactivity of Naphthols in Asymmetric Dearomatization or O-Alkylation Reactions with Aziridines
Linqing Wang et al.
ADVANCED SYNTHESIS & CATALYSIS (2018)
Biocatalytic Desymmetrization of Prochiral 3-Aryl and 3-Arylmethyl Glutaramides: Different Remote Substituent Effect on Catalytic Efficiency and Enantioselectivity
Yu-Fei Ao et al.
ADVANCED SYNTHESIS & CATALYSIS (2018)
Chiral Carboxylic Acid Enabled Achiral Rhodium(III)-Catalyzed Enantioselective C-H Functionalization
Luqing Lin et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)
Enantioselective acyl-transfer catalysis by fluoride ions
Ryan Craig et al.
CHEMICAL COMMUNICATIONS (2018)
Enantioselective Desymmetrization of 1,3-Diols by a Chiral DMAP Derivative
Hiroki Mandai et al.
CHEMISTRY LETTERS (2018)
Enantioselective remote meta-C-H arylation and alkylation via a chiral transient mediator
Hang Shi et al.
NATURE (2018)
Chiral Aryliodine-Catalyzed Asymmetric Oxidative C-N Bond Formation via Desymmetrization Strategy
Qiang Ding et al.
ORGANIC LETTERS (2018)
Preparation of (1R,4S)-4-hydroxycyclopent-2-en-1-yl acetate via Novozym-435® catalyzed desymmetrization of cis-3,5-Diacetoxy-1-cyclopentene
Shekhar Putta et al.
TETRAHEDRON (2018)
Reversible Switching and Recycling of Adaptable Organic Microgel Catalysts (Microgelzymes) for Asymmetric Organocatalytic Desymmetrization
Ruediger Borrmann et al.
ACS CATALYSIS (2018)
Scoping the Enantioselective Desymmetrization of a Poorly Water-Soluble Diester by Recombinant Pig Liver Esterase
Murray P. Meissner et al.
ORGANIC PROCESS RESEARCH & DEVELOPMENT (2018)
Chiral Pentacarboxycyclopentadiene-Based Bronsted AcidCatalyzed Enantioselective Desymmetrization of Meso-Epoxides by 2-Mercaptobenzothiazoles
Chao Yuan et al.
ACS OMEGA (2018)
Directed Rh-I-Catalyzed Asymmetric Hydroboration of Prochiral 1-Arylcycloprop-2-Ene-1-Carboxylic Acid Derivatives
Andrew Edwards et al.
CHEMISTRY-A EUROPEAN JOURNAL (2018)
Synthesis of Chiral Vicinal Diamines by Silver(I)-Catalyzed Enantioselective Aminolysis of N-Tosylaziridines
Zhuo Chai et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds
Bo Su et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
Enantioselective Oxidative Ring-Opening Reaction of Aziridines with α-Nitroesters Using Cinchona Alkaloid Amide/Nickel(II) Catalysts
Noriyuki Shiomi et al.
ORGANIC LETTERS (2017)
The Construction of Chiral Fused Azabicycles Using a Pd-Catalyzed Allylic Substitution Cascade and Asymmetric Desymmetrization Strategy
Qianjin An et al.
ORGANIC LETTERS (2017)
Cinchona Alkaloid Derived Primary Amine Catalyzed Intramolecular Desymmetrizing Aldolization Reaction of Diacetonyloxindoles
Bing-Bing Sun et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2017)
Local Desymmetrization through Diastereotopic Group Selection: An Enabling Strategy for Natural Product Synthesis
Matthew A. Horwitz et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2017)
Desymmetrization of meso-1,2-Diols by a Chiral N,N-4-Dimethylaminopyridine Derivative Containing a 1,1'-Binaphthyl Unit: Importance of the Hydroxy Groups
Hiroki Mandai et al.
JOURNAL OF ORGANIC CHEMISTRY (2017)
Enantioselective Synthesis of Chiral Oxygen-Containing Heterocycles Using Copper-Catalyzed Aryl C-O Coupling Reactions via Asymmetric Desymmetrization
Yong Zhang et al.
JOURNAL OF ORGANIC CHEMISTRY (2017)
Asymmetric Ring-Opening Reactions of Aza- and Oxa-bicyclic Alkenes with Boronic Acids Using a Palladium/Zinc Co-catalytic System
Wei Zhang et al.
JOURNAL OF ORGANIC CHEMISTRY (2017)
A Theoretical Mechanistic Study of the Asymmetric Desymmetrization of a Cyclic meso-Anhydride by a Bifunctional Quinine Sulfonamide Organocatalyst
Katie Blise et al.
JOURNAL OF ORGANIC CHEMISTRY (2017)
Iridium-Catalyzed Anti-Stereoselective Asymmetric Ring-Opening Reactions of Azabenzonorbornadienes with Carboxylic Acids
Meina Zhu et al.
JOURNAL OF ORGANIC CHEMISTRY (2017)
Desymmetrization of Diarylmethylamido Bis(phenols) through Peptide-Catalyzed Bromination: Enantiodivergence as a Consequence of a 2 amu Alteration at an Achiral Residue within the Catalyst
Anna E. Hurtley et al.
JOURNAL OF ORGANIC CHEMISTRY (2017)
Enantioselective Intermolecular C-O Bond Formation in the Desymmetrization of Diarylmethines Employing a Guanidinylated Peptide-Based Catalyst
Alex J. Chinn et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)
Diastereodivergent Asymmetric Carboamination/Annulation of Cyclopropenes with Aminoalkenes by Chiral Lanthanum Catalysts
Huai-Long Teng et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)
Asymmetric Nitrone Synthesis via Ligand-Enabled Copper-Catalyzed Cope-Type Hydroamination of Cyclopropene with Oxime
Zhanyu Li et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)
Enantioselective Palladium-Catalyzed Intramolecular α-Arylative Desymmetrization of 1,3-Diketones
Chendan Zhu et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)
Pd(II)-Catalyzed Enantioselective C(sp3)-H Borylation
Jian He et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)
Cobalt Catalysis for Enantioselective Cyclobutanone Construction
Daniel K. Kim et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)
Manipulating the stereoselectivity of the thermostable Baeyer-Villiger monooxygenase TmCHMO by directed evolution
Guangyue Li et al.
ORGANIC & BIOMOLECULAR CHEMISTRY (2017)
Magnesium Catalysis Mediated Tetrazoles in Desymmetrization Reaction of Aziridines
Dan Li et al.
ORGANIC LETTERS (2017)
Construction of Distant Stereocenters by Enantioselective Desymmetrizing Carbonyl-Ene Reaction
Weiwei Luo et al.
ORGANIC LETTERS (2017)
Enantioselective Synthesis of 4′-Ethynyl-2-fluoro-2′-deoxyadenosine (EFdA) via Enzymatic Desymmetrization
Mark McLaughlin et al.
ORGANIC LETTERS (2017)
Synthetic Study on Pactamycin: Stereoselective Synthesis of the Cyclopentane Core Framework
Atsumi Goto et al.
ORGANIC LETTERS (2017)
Iridium-Catalyzed Anti-Stereoselective Ring-Opening Reactions of Azabicyclic Alkenes with Fluoroalkylamines
Wen Yang et al.
SYNTHESIS-STUTTGART (2017)
Catalytic Enantioselective Desymmetrization of Meso Compounds in Total Synthesis of Natural Products: Towards an Economy of Chiral Reagents
Jeremy Merad et al.
SYNTHESIS-STUTTGART (2017)
Preparation of (2R, 3R, 4R)-3-hydroxy-2,4,6-trimethylheptanoic acid via enzymatic desymmertization
Yoshinori Tokairin et al.
TETRAHEDRON (2017)
Recent topics in the desymmetrization of meso-diols
Takeyuki Suzuki
TETRAHEDRON LETTERS (2017)
Rhodium/zinc co-catalyzed asymmetric ring opening reactions of oxabenzonorbornadienes with carboxylic acids
Xiaobo He et al.
TETRAHEDRON-ASYMMETRY (2017)
Enantioselective Medium-Ring Lactone Synthesis through an NHC-Catalyzed Intramolecular Desymmetrization of Prochiral 1,3-Diols
Zijun Wu et al.
ACS CATALYSIS (2017)
Palladium-Catalyzed Enantioselective C(sp2)-H lmidoylation by Desymmetrization
Jian Wang et al.
ACS CATALYSIS (2017)
Ketene Aminal Phosphates: Competent Substrates for Enantioselective Pd(0)-Catalyzed C-H Functionalizations
Dania Grosheva et al.
ACS CATALYSIS (2017)
Platinum-catalyzed syn-stereocontrolled ring-opening of oxabicyclic alkenes with sodium arylsulfinates
Ruihua Wu et al.
ORGANIC CHEMISTRY FRONTIERS (2017)
Non-Covalent Carbonyl-Directed Heck-Matsuda Desymmetrizations: Synthesis of Cyclopentene-Fused Spirooxindoles, Spirolactones, and Spirolactams
Shivashankar Kattela et al.
ADVANCED SYNTHESIS & CATALYSIS (2017)
Design and Fabrication of Temperature-Sensitive Nanogels with Controlled Drug Release Properties for Enhanced Photothermal Sterilization
Luoyuan Li et al.
CHEMISTRY-A EUROPEAN JOURNAL (2017)
Desymmetrization of Bisallylic Amides through Catalytic Enantioselective Bromocyclization with BINAP Monoxide
Yoshihiro Nagao et al.
CHEMISTRY-A EUROPEAN JOURNAL (2017)
Iridium-Catalyzed Asymmetric Allylic Dearomatization by a Desymmetrization Strategy
Ye Wang et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
Chiral Magnesium(II) Complex-Catalyzed Enantioselective Desymmetrization of meso-Aziridines with Pyrazoles
Xiangqiang Li et al.
ADVANCED SYNTHESIS & CATALYSIS (2017)
Enantioselective Total Synthesis of (-)-Deoxoapodine
Taek Kang et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
Asymmetric Yttrium-Catalyzed C(sp3)-H Addition of 2-Methyl Azaarenes to Cyclopropenes
Yong Luo et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
Enantioselective Propargylation of Polyols and Desymmetrization of meso 1,2-Diols by Copper/Borinic Acid Dual Catalysis
Ren-Zhe Li et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
Enantioselective Borylation of Aromatic C-H Bonds with Chiral Dinitrogen Ligands
Bo Su et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
Asymmetric Copper-Catalyzed Carbomagnesiation of Cyclopropenes
Longyang Dian et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
Enantioselective Silver and Amine Co-catalyzed Desymmetrizing Cycloisomerization of Alkyne-Linked Cyclohexanones
Ruben Manzano et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
Enantioselective Heck-Matsuda Arylations through Chiral Anion Phase-Transfer of Aryl Diazonium Salts
Carolina M. Avila et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
A catalytic enantioselective approach to tetrol bearing vicinal all-carbon quaternary stereogenic centers
Hui Yang et al.
CHEMICAL COMMUNICATIONS (2017)
Desymmetrization of aziridine with malononitrile using cinchona alkaloid amide/zinc(II) catalysts
Noriyuki Shiomi et al.
CHEMICAL COMMUNICATIONS (2017)
Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso-Anhydrides
Erin E. Stache et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
Enantioselective Synthesis of Chiral Oxime Ethers: Desymmetrization and Dynamic Kinetic Resolution of Substituted Cyclohexanones
Sri Krishna Nimmagadda et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
Cooperative Lewis acid-onium salt catalysis as tool for the desymmetrization of meso-epoxides
Florian Broghammer et al.
CHEMICAL COMMUNICATIONS (2017)
A Stereocontrolled Synthesis of the C11-C24 Fragment of InostamycinA via the Desymmetrization of Glycerols
Guangri Yu et al.
ASIAN JOURNAL OF ORGANIC CHEMISTRY (2016)
A Catalyst-Directed Remote Stereogenic Center Switch During the Site-Selective Aldol Desymmetrization of Cyclohexanone-Based Diketones
Thomas C. Nugent et al.
ADVANCED SYNTHESIS & CATALYSIS (2016)
P450 BM3 Monooxygenase as an Efficient NAD(P)H-Oxidase for Regeneration of Nicotinamide Cofactors in ADH-Catalysed Preparative Scale Biotransformations
Claudia Holec et al.
ADVANCED SYNTHESIS & CATALYSIS (2016)
Enantioselective Ring Opening Reactions of Azabenzonorbornadienes with Carboxylic Acids
Yongyun Zhou et al.
ADVANCED SYNTHESIS & CATALYSIS (2016)
Exploiting Distal Reactivity of Coumarins: A Rhodium-Catalyzed Vinylogous Asymmetric Ring-Opening Reaction
Charles C. J. Loh et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)
Synthesis of Chiral Aminocyclopropanes by Rare-Earth-Metal-Catalyzed Cyclopropene Hydroamination
Huai-Long Teng et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)
Enantioselective Synthesis of Cyclobutylboronates via a Copper-Catalyzed Desymmetrization Approach
Manuel Guisan-Ceinos et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)
Rhodium-Catalyzed Desymmetrization by Hydroformylation of Cyclopentenes: Synthesis of Chiral Carbocyclic Nucleosides
Cai You et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)
Dysprosium(III)-Catalyzed Ring-Opening of meso-Epoxides: Desymmetrization by Remote Stereocontrol in a Thiolysis/Elimination Sequence
Lu Yao et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)
Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds
Taegyo Lee et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)
Synthesis and biological evaluation of enantiomerically pure glyceric acid derivatives as LpxC inhibitors
Giovanni Tangherlini et al.
BIOORGANIC & MEDICINAL CHEMISTRY (2016)
N-Heterocyclic carbene-catalyzed desymmetrization of functionalized 1,4-dienes via Stetter Reaction
Qiqiao Lin et al.
CHEMICAL COMMUNICATIONS (2016)
Two-step desymmetrization of dipyrazolidyl 3-phenylglutarate via lipase-catalyzed hydrolysis in organic solvents
Po-Hao Chan et al.
CHEMICAL ENGINEERING SCIENCE (2016)
Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters
Xing-Ping Zeng et al.
CHEMICAL REVIEWS (2016)
Copper mediated carbometalation reactions
D. S. Mueller et al.
CHEMICAL SOCIETY REVIEWS (2016)
Organocatalytic enantioselective desymmetrisation
A. Borissov et al.
CHEMICAL SOCIETY REVIEWS (2016)
Monomeric Cinchona Alkaloid-Based Catalysts for Highly Enantioselective Bromolactonisation of Alkynes
Michael Wilking et al.
CHEMISTRY-A EUROPEAN JOURNAL (2016)
MgII-Catalyzed Desymmetrization Reaction of meso-Aziridines with Hydroxylamines: Synthesis of Novel Chiral 1,2-Diamine Skeletons
Dan Li et al.
CHEMISTRY-A EUROPEAN JOURNAL (2016)
Beyond Chemoselectivity: Catalytic Site-Selective Aldolization of Diketones and Exploitation for Enantioselective Alzheimer's Drug Candidate Synthesis
Thomas C. Nugent et al.
CHEMISTRY-A EUROPEAN JOURNAL (2016)
Ring-Opening Regio-, Diastereo-, and Enantioselective 1,3 Chlorochalcoge nation of Cyclopropyl Carbaldehydes
Jan Wallbaum et al.
CHEMISTRY-A EUROPEAN JOURNAL (2016)
Organocatalytic Asymmetric Reactions of Epoxides: Recent Progress
Sara Meninno et al.
CHEMISTRY-A EUROPEAN JOURNAL (2016)
Catalytic Asymmetric Ring-Opening Reactions of Aziridines with 3-Aryl-Oxindoles
Linqing Wang et al.
CHEMISTRY-AN ASIAN JOURNAL (2016)
Simple Preparation of Rhodococcus erythropolis DSM 44534 as Biocatalyst to Oxidize Diols into the Optically Active Lactones
Enriqueta Martinez-Rojas et al.
CHIRALITY (2016)
Organocatalytic Enantioselective Desymmetrization of meso-Aziridines and Prochiral Azetidines
Zhaobin Wang et al.
CURRENT ORGANIC CHEMISTRY (2016)
Enantioselective Syntheses of (-)-Alloyohimbane and (-)-Yohimbane by an Efficient Enzymatic Desymmetrization Process
Arun K. Ghosh et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2016)
Chemoenzymatic Synthesis of Chiral 1-Benzyl-5-(hydroxymethyl)-2-piperidone Enabled by Lipase AK-Mediated Desymmetrization of Prochiral 1,3-Diol and Its Diacetate
Duc Thinh Khong et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2016)
Enantio- and diastereoselective acylation of prochiral hydroxyl group of pyrimidine acyclonucleosides
Renata Kolodziejska et al.
JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC (2016)
A Bronsted Acid-Amino Acid as a Synergistic Catalyst for Asymmetric List-Lerner-Barbas Aldol Reactions
Dhevalapally B. Ramachary et al.
JOURNAL OF ORGANIC CHEMISTRY (2016)
Formal Total Synthesis of Amphidinolide Q
Vivek K. Mishra et al.
JOURNAL OF ORGANIC CHEMISTRY (2016)
Intermolecular Noncovalent Hydroxy-Directed Enantioselective Heck Desymmetrization of Cyclopentenol: Computationally Driven Synthesis of Highly Functionalized cis-4-Arylcyclopentenol Scaffolds
Juliana de Oliveira Silva et al.
JOURNAL OF ORGANIC CHEMISTRY (2016)
Total Synthesis of (+)-Mesembrine Applying Asymmetric Gold Catalysis
Michael Spittler et al.
JOURNAL OF ORGANIC CHEMISTRY (2016)
Chiral-Substituted Poly-N-vinylpyrrolidinones and Bimetallic Nanoclusters in Catalytic Asymmetric Oxidation Reactions
Bo Hao et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)
Nickel-Catalyzed Asymmetric Kumada Cross-Coupling of Symmetric Cyclic Sulfates
Meredith S. Eno et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)
Distal Stereocontrol Using Guanidinylated Peptides as Multifunctional Ligands: Desymmetrization of Diarylmethanes via Ullman Cross-Coupling
Byoungmoo Kim et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)
Palladium/L-Proline-Catalyzed Enantioselective α-Arylative Desymmetrization of Cyclohexanones
Ren-Rong Liu et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)
Rhodium-Catalyzed Enantioselective Cycloisomerization to Cyclohexenes Bearing Quaternary Carbon Centers
Jung-Woo Park et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)
Concise Total Syntheses of (+)-Haplocidine and (+)-Haplocine via Late-Stage Oxidation of (+)-Fendleridine Derivatives
Kolby L. White et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)
Enantioselective Nickel-Catalyzed anti-Carbometallative Cyclizations of Alkynyl Electrophiles Enabled by Reversible Alkenylnickel E/Z Isomerization
Christopher Clarke et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)
Design, synthesis and in vitro splicing inhibition of desmethyl and carba-derivatives of herboxidiene
Arun K. Ghosh et al.
ORGANIC & BIOMOLECULAR CHEMISTRY (2016)
Enantioselective total synthesis of the highly selective sphingosine-1-receptor VPC01091 by the Heck desymmetrization of a non-activated cyclopentene-fused spiro-pyrrolidinone
Ismat Ullah Khan et al.
ORGANIC & BIOMOLECULAR CHEMISTRY (2016)
Rhodium-catalyzed asymmetric ring opening reaction of oxabenzonorbornadienes with amines using ZnI2 as the activator
Xin Xu et al.
ORGANIC & BIOMOLECULAR CHEMISTRY (2016)
A Second-Generation Synthesis of the Cyanthiwigin Natural Product Core
Kelly E. Kim et al.
ORGANIC LETTERS (2016)
Catalytic Enantioselective Desymmetrization of Norbornenoquinones via C(sp2)-H Alkylation
Rahul Sarkar et al.
ORGANIC LETTERS (2016)
Kinetic Separation and Asymmetric Reactions of Norcaradiene Cycloadducts: Facilitated Access via H2O-Accelerated Cycloaddition
William D. Mackay et al.
ORGANIC LETTERS (2016)
Ru-Catalyzed Asymmetric Hydrogenative/Transfer Hydrogenative Desymmetrization of Meso-Epoxy Diketones
Yuping Hong et al.
ORGANIC LETTERS (2016)
Stereoselective Rh-Catalyzed Hydrogenative Desymmetrization of Achiral Substituted 1,4-Dienes
Hector Fernandez-Perez et al.
ORGANIC LETTERS (2016)
Access to Cyclopropyl-Fused Azacycles via a Palladium-Catalyzed Direct Alkenylation Strategy
Carolyn L. Ladd et al.
ORGANIC LETTERS (2016)
Iridium-Catalyzed Asymmetric Addition of Thiophenols to Oxabenzonorbornadienes
Sifeng Li et al.
ORGANIC LETTERS (2016)
Palladium/Lewis Acid Co-catalyzed Divergent Asymmetric Ring-Opening Reactions of Azabenzonorbornadienes with Alcohols
Fan Yang et al.
ORGANIC LETTERS (2016)
Development of a Scalable Synthesis of an Azaindolyl-Pyrimidine Inhibitor of Influenza Virus Replication
Jianglin Liang et al.
ORGANIC PROCESS RESEARCH & DEVELOPMENT (2016)
Recombinant Pig Liver Esterase-Catalyzed Synthesis of (1S,4R)-4-Hydroxy-2-cyclopentenyl Acetate Combined with Subsequent Enantioselective Crystallization
Janine Hinze et al.
ORGANIC PROCESS RESEARCH & DEVELOPMENT (2016)
An aromatic ion platform for enantioselective Bronsted acid catalysis
Chirag D. Gheewala et al.
SCIENCE (2016)
Palladium-Catalyzed Wacker-Type Oxidation of N-Boc Indoles under Mild Conditions
Xiao-Yu Zhou et al.
SYNLETT (2016)
Phosphoric Acid Based Heterodimers in Asymmetric Catalysis
Mattia R. Monaco et al.
SYNLETT (2016)
Enantio-and diastereoselective desymmetrization of α-alkyl-α-diazoesters by dirhodium(II)-catalyzed intramolecular C-H insertion
Taku Miyazawa et al.
TETRAHEDRON (2016)
Desymmetrization of acid anhydride with asymmetric esterification catalyzed by chiral phosphoric acid
Ken-ichi Yamada et al.
TETRAHEDRON LETTERS (2016)
Chiral copper-catalyzed asymmetric monoarylation of vicinal diols with diaryliodonium salts
Norihisa Hamaguchi et al.
TETRAHEDRON-ASYMMETRY (2016)
Syntheses and odor properties of optically active dimethyl octenone and its analogs
Masashi Kawasaki et al.
TETRAHEDRON-ASYMMETRY (2016)
Enantioselective acyl transfer catalysis by a combination of common catalytic motifs and electrostatic interactions
Hiroki Mandai et al.
NATURE COMMUNICATIONS (2016)
Palladium-Catalyzed, Enantioselective Heine Reaction
Molly Punk et al.
ACS CATALYSIS (2016)
Structure-Guided Triple-Code Saturation Mutagenesis: Efficient Tuning of the Stereoselectivity of an Epoxide Hydrolase
Zhoutong Sun et al.
ACS CATALYSIS (2016)
Multiparameter Optimization in Directed Evolution: Engineering Thermostability, Enantioselectivity, and Activity of an Epoxide Hydrolase
Guangyue Li et al.
ACS CATALYSIS (2016)
Tao-Phos-controlled desymmetrization of succinimide-based bisalkynes via asymmetric copper-catalyzed Huisgen alkyne-azide click cycloaddition: substrate scope and mechanism
Mu-Yi Chen et al.
RSC ADVANCES (2016)
Synthesis of cinchona alkaloid sulfonamide polymers as sustainable catalysts for the enantioselective desymmetrization of cyclic anhydrides
Shohei Takata et al.
RSC ADVANCES (2016)
(S)-2-[(N-arylamino)methyl]pyrrolidines-Based Phosphoramidite P,N-Ligand Library for Asymmetric Metal-Catalyzed Allylic Substitution and Conjugate 1,4-Addition
Konstantin N. Gavrilov et al.
CHEMISTRYSELECT (2016)
A review of solifenacin in the treatment of urinary incontinence
Con Kelleher
Therapeutics and Clinical Risk Management (2016)
Dinuclear zinc-catalyzed desymmetric intramolecular aldolization: an enantioselective construction of spiro[cyclohexanone-oxindole] derivatives
Ya-Fei Zhang et al.
RSC ADVANCES (2016)
Enantioselective Synthesis of α,α-Disubstituted Lactones via a Chiral Bronsted Acid Catalyzed Intramolecular Cyclization
Jennifer E. Wilent et al.
ORGANIC SYNTHESES (2016)
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)
Copper-Catalyzed Intramolecular Desymmetric Aryl CO Coupling for the Enantioselective Construction of Chiral Dihydrobenzofurans and Dihydrobenzopyrans
Wenqiang Yang et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)
Catalytic Silylations of Alcohols: Turning Simple Protecting-Group Strategies into Powerful Enantioselective Synthetic Methods
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CHEMCATCHEM (2015)
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Organocatalytic Enantioselective Formal C(sp2)-H Alkylation
Madhu Sudan Manna et al.
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Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings
Osvaldo Gutierrez et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)
Catalytic asymmetric desymmetrization approaches to enantioenriched cyclopentanes
Madhu Sudan Manna et al.
ORGANIC & BIOMOLECULAR CHEMISTRY (2015)
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ORGANIC LETTERS (2015)
Chemoenzymatic Sequential Multistep One-Pot Reaction for the Synthesis of (1S,2R)-1-(Methoxycarbonyl)cyclohex-4-ene-2-carboxylic Acid with Recombinant Pig Liver Esterase
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ORGANIC PROCESS RESEARCH & DEVELOPMENT (2015)
Nonenzymatic enantioselective synthesis of all-carbon quaternary centers through desymmetrization
Kimberly S. Petersen
TETRAHEDRON LETTERS (2015)
Rh-catalyzed desymmetrization of α-quaternary centers by isomerization-hydroacylation
Jung-Woo Park et al.
CHEMICAL SCIENCE (2015)
Enantioselective Copper-Catalyzed Azide-Alkyne Click Cycloaddition to Desymmetrization of Maleimide-Based Bis(alkynes)
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CHEMISTRY-A EUROPEAN JOURNAL (2015)
Stereoselective Synthesis of Aryl Cyclopentene Scaffolds by Heck-Matsuda Desymmetrization of 3-Cyclopentenol
Ricardo A. Angnes et al.
CHEMISTRY-A EUROPEAN JOURNAL (2014)
Enantioselective Desymmetrization of Diesters
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N-Substituted 2-Aminobiphenylpalladium Methanesulfonate Precatalysts and Their Use in C-C and C-N Cross-Couplings
Nicholas C. Bruno et al.
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Palladium(II)-Catalyzed Enantioselective C(sp3)-H Activation Using a Chiral Hydroxamic Acid Ligand
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Copper-Catalyzed Diastereo- and Enantioselective Desymmetrization of Cyclopropenes: Synthesis of Cyclopropylboronates
Alejandro Parra et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Scale-Up of a Recombinant Pig Liver Esterase-Catalyzed Desymmetrization of Dimethyl Cyclohex-4-ene-cis-1,2-dicarboxylate
Philipp Suess et al.
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Asymmetric, Organocatalytic Bromolactonization of Allenoic Acids
Michael Wilking et al.
SYNLETT (2014)
Desymmetrization as a Strategy in Asymmetric Halocyclization Reactions
Ulrich Hennecke et al.
SYNLETT (2014)
Catalytic Enantioselective Desymmetrizations of Prochiral Dienone Systems
Gaetan Maertens et al.
SYNTHESIS-STUTTGART (2014)
Asymmetric transformations of achiral 2,5-cyclohexadienones
Kyle A. Kalstabakken et al.
TETRAHEDRON (2014)
Recent advances of desymmetrization protocol applied in natural product total synthesis
Ming Wang et al.
TETRAHEDRON LETTERS (2014)
Synthetic methodologies of achiral diarylmethanols, diaryl and triarylmethanes (TRAMs) and medicinal properties of diaryl and triarylmethanes-an overview
Sankalan Mondal et al.
RSC ADVANCES (2014)
Catalytic enantioselective reductive desymmetrisation of achiral and meso compounds
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CHEMICAL COMMUNICATIONS (2013)
Enantioselective, Desymmetrizing Bromolactonization of Alkynes
Michael Wilking et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)
Asymmetric Copper(I)-Catalyzed Azide-Alkyne Cycloaddition to Quaternary Oxindoles
Feng Zhou et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)
Total Synthesis of (-)-18-epi-Peloruside A: An Alkyne Linchpin Strategy
Barry M. Trost et al.
ORGANIC LETTERS (2013)
Pd-Catalyzed Desymmetric Intramolecular O-Arylation Reaction: Enantioselective Synthesis of (3,4-Dihydro-2H-chromen-3-yl)methanols
Wenqiang Yang et al.
ORGANIC LETTERS (2013)
Chiral 1,1-diaryl compounds as important pharmacophores
Dana Ameen et al.
MEDCHEMCOMM (2013)
Catharanthine Dilates Small Mesenteric Arteries and Decreases Heart Rate and Cardiac Contractility by Inhibition of Voltage-Operated Calcium Channels on Vascular Smooth Muscle Cells and Cardiomyocytes
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The δ Opioid Receptor Agonist SNC80 Selectively Activates Heteromeric μ-δ Opioid Receptors
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ACS CHEMICAL NEUROSCIENCE (2012)
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)
Organocatalyzed Enantioselective Desymmetrization of Diols in the Preparation of Chiral Building Blocks
Maria D. Diaz-de-Villegas et al.
CHEMISTRY-A EUROPEAN JOURNAL (2012)
Copper-Catalyzed Desymmetric Intramolecular Ullmann C-N Coupling: An Enantioselective Preparation of Indolines
Fengtao Zhou et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
Bifunctional Catalyst Promotes Highly Enantioselective Bromolactonizations To Generate Stereogenic C-Br Bonds
Daniel H. Paull et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
The Wieland-Miescher Ketone: A Journey from Organocatalysis to Natural Product Synthesis
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SYNLETT (2012)
The first examples of the enantioselective Heck-Matsuda reaction: arylation of unactivated cyclic olefins using chiral bisoxazolines
Carlos Roque D. Correia et al.
TETRAHEDRON LETTERS (2012)
Cyclopropyl Iminium Activation: Reactivity Umpolung in Enantioselective Organocatalytic Reaction Design
Christof Sparr et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)
Organocatalytic Enantioselective Acyl Transfer onto Racemic as well as meso Alcohols, Amines, and Thiols
Christian E. Mueller et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)
Asymmetric catalysis with peptides
Helma Wennemers
CHEMICAL COMMUNICATIONS (2011)
Update 1 of: Enantioselective Enzymatic Desymmetrizations in Organic Synthesis
Eduardo Garcia-Urdiales et al.
CHEMICAL REVIEWS (2011)
The Catalytic Asymmetric Fischer Indolization
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)
Enantioselective Alcoholysis of meso-Glutaric Anhydrides Catalyzed by Cinchona-Based Sulfonamide Catalysts
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ADVANCED SYNTHESIS & CATALYSIS (2010)
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)
Chiral Bronsted acid catalyzed asymmetric Baeyer-Villiger reaction of 3-substituted cyclobutanones by using aqueous H2O2
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)
Primary-amine-catalyzed enantioselective intramolecular aldolizations
Jian Zhou et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)
A highly reactive and enantioselective bifunctional organocatalyst for the methanolytic desymmetrization of cyclic anhydrides: Prevention of catalyst aggregation
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)
Metal-catalyzed enantioselective allylation in asymmetric synthesis
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)
Physicochemical, Pharmacological and Pharmacokinetic Properties of the Zwitterionic Antihistamines Cetirizine and Levocetirizine
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CURRENT MEDICINAL CHEMISTRY (2008)
Rhodium-catalyzed hydroformylation of cyclopropenes
William M. Sherrill et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)
The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation
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NATURE (2008)
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)
Rhodium-catalyzed ring-opening reactions of N-boc-azabenzonorbornadienes with amine nucleophiles
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)
Formal synthesis of (+)-catharanthine
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)
Desymmetrization and diastereotopic group selection in 1,4-cyclohexadienes
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SYNLETT (2005)
Catalytic enantioselective hydrostannation of cyclopropenes
M Rubina et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)
Assignment of absolute stereochemistry and total synthesis of (-)-spongidepsin
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ORGANIC LETTERS (2004)
An alkaloid-mediated desymmetrization of meso-anhydrides via a nucleophilic ring opening with benzyl alcohol and its application in the synthesis of highly enantiomerically enriched β-amino acids
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TETRAHEDRON-ASYMMETRY (2003)
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M Rubina et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)
Transition metal-catalyzed enantioselective ring-opening reactions of oxabicyclic alkenes
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ACCOUNTS OF CHEMICAL RESEARCH (2003)
BINOLAM, a recoverable chiral ligand for bifunctional enantioselective catalysis:: The asymmetric synthesis of cyanohydrins
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ORGANIC LETTERS (2002)
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