Journal
SYNTHESIS-STUTTGART
Volume 54, Issue 12, Pages 2799-2815Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1767-3026
Keywords
ferrocene; phosphonates; copper catalysis; cross-coupling; deprotolithiation
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Funding
- Universite de Rennes 1, Centre National de la Recherche Scientifique (CNRS)
- University of Carthage
- Ministere de l'Enseignement Superieur et de la Recherche Scientifique (Tunisian Ministry of Higher Education and Scientific Research)
- Fonds Europeen de Developpement Regional (FEDER)
- European Regional Development Fund
- D8 VENTURE Bruker AXS diffractometer
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This article presents a method for the synthesis of ferrocenephosphonates and describes further functionalization through regioselective deprotolithiation and Negishi and Suzuki-Miyaura cross-coupling reactions. These findings provide important insights and foundations for organic synthesis and coordination chemistry.
Ferrocenephosphonates make up an important class of organometallic derivatives with a wide range of useful applications in organic synthesis and coordination chemistry. Here, an approach to ferro-cenephosphonates based on a copper-promoted Hirao coupling is reported. Further functionalizations based on regioselective deprotolithiation and both Negishi and Suzuki-Miyaura cross-coupling reactions are also described to reach original derivatives.
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