4.7 Article

A simple and effective resin pre-coating treatment on grinded, acid pickled and anodised substrates for stronger adhesive bonding between Ti-6Al-4V titanium alloy and CFRP

Journal

SURFACE & COATINGS TECHNOLOGY
Volume 432, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2021.128072

Keywords

Carbon fibre reinforced polymer (CFRP); Titanium alloy; Adhesive bonding; Surface modification; Resin pre-coating

Funding

  1. Fundamental Research Funds of Southwestern University of Science and Technology [20zx7141]
  2. National Natural Science Foundation of China [52102115]

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This study investigated the performance of different surface treatments for adhesive bonding between carbon fibre reinforced polymer (CFRP) and titanium alloy. Acid pickling, grinding, anodising treatments, and resin pre-coating (RPC) were employed. The results showed that grinding and anodised specimens had higher bond strengths than acid pickled specimens. RPC treatment significantly increased bond strengths, especially on rough surfaces. The combination of NaOH anodising and RPC treatment yielded the highest bond strength and changed the failure mode.
Adhesive bonding between carbon fibre reinforced polymer (CFRP) and titanium alloy is extensively employed to achieve lightweight and adequate strength in aircraft structures. In this study, acid pickling, grinding and anodising treatments were applied to the Ti-6Al-4V titanium substrates, and the CFRPs were grinded to compare the performances. A special technique named resin pre-coating (RPC) was also used to improve substrate wetting. The single lap shear tests results showed that the bond strengths of grinded and anodised specimens were higher than that of the acid pickled specimens. The RPC treatment further increased the bond strengths of all the specimens by 29.9%-51.5% and appeared to be more effective on rough surfaces. A combination of the NaOH anodising and RPC treatment yielded the highest bond strength of 22.0 MPa, which was 105.3% and 70.1% higher than the bond strengths of acid pickled and grinded specimens, respectively, and the failure mode changed from adhesive failure to CFRP delamination failure. These surface treatments are simple and thus suitable for aerospace and aviation industries.

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