A dual-emission polymer carbon nanoparticles for ratiometric and visual detection of pH value and bilirubin

Herein, we prepared a novel fluorescent polymer carbon nanoparticles by polymerizing dopamine (DA) and o-phenylenediamine (OPD) through oxidation of hydrogen peroxide. In a neutral environment, the synthesized fluorescent polymer carbon nanoparticles (PDA-OPD) exhibited two emission peaks at 460 nm and 540 nm with 400 nm excitation wavelength. In an acidic environment, the fluorescence emission peaks of PDA-OPD at 540 nm showed an obvious fluorescence quenching, and there existed a good linear relationship between the fluorescence ratio F-540/F-460 and environment pH value. In an alkaline environment, the fluorescence emission peak at 460 nm showed obvious fluorescence quenching after the addition of bilirubin, while a novel fluorescence emission peak at 560 nm emerged gradually. The PDA-OPD could be also used to detect bilirubin in the range of 0-400 mu mol.L-1. (C) 2021 Elsevier B.V. All rights reserved.

Automated summary

A novel fluorescent polymer carbon nanoparticle (PDA-OPD) was prepared by polymerizing dopamine and o-phenylenediamine through oxidation reaction, showing different fluorescence properties in neutral, acidic, and alkaline environments, and capable of detecting bilirubin effectively.