4.5 Article

Tunable TTB strontium and tantalum based thin films: Influence of the deposition parameters on the structural and dielectric properties

Journal

SOLID STATE SCIENCES
Volume 121, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.solidstatesciences.2021.106733

Keywords

Perovskite phase; TTB phase; Thin films; Crystallization; Dielectric characterization; Tunability

Funding

  1. European Union through the European Regional Development Fund (ERDF)
  2. French Ministry of Higher Education and Research, Brittany Region
  3. Cotes d'Armor Departement through the CPER Projects
  4. Conseil Departemental des Cotes d'Armor, Saint Brieuc Armor Agglomeration
  5. Syndicat de Gestion du Pole Universitaire de Saint Brieuc (France)

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The structural and dielectric properties of thin films produced by reactive radiofrequency sputtering of a (Sr2Ta2O7)(100-x) (La2Ti2O7)(x) target with x = 1.65 were studied. It was found that the highest permittivities and tunabilities are associated with the pure and fully textured films. This was achieved for a 900 nm thick film deposited at T-s = 850 degrees C.
Structural and dielectric properties of thin films produced by reactive radiofrequency sputtering of a (Sr2Ta2O7)(100-x) (La2Ti2O7)(x) target with x = 1.65 were studied. The chemical composition characterization shows Sr/Ta ratios ranging between 0.49 and 0.56, thus pointing out the deposition of strontium deficient films, belonging to the tetragonal tungsten bronze family. The highest permittivities and tunabilities, associated with the lowest dielectric losses, are obtained when films are pure and fully textured. This is achieved for a 900 nmthick film deposited at T-s = 850 degrees C: epsilon' = 116, tan delta = 0.007 and tunability T = 14.5% at 340 kV/cm and 100 kHz.

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