Journal
SMALL
Volume 18, Issue 5, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.202104506
Keywords
flexible; ink; lithium ion micro-batteries; screen printing; wearable electronics
Categories
Funding
- National Key R@D Program of China [2016YFB0100100]
- National Natural Science Foundation of China [22075279, 22125903, 51872283, 21805273]
- Liao Ning Revitalization Talents Program [XLYC1807153]
- Liaoning BaiQianWan Talents Program
- Dalian Innovation Support Plan for High Level Talents [2019RT09]
- central government of Liaoning Province [2021JH6/10500112]
- Dalian National Laboratory For Clean Energy (DNL)
- CAS
- DNL Cooperation Fund
- CAS [DNL201912, DNL201915, DNL202016, DNL202019]
- DICP [DICP ZZBS201708, DICP ZZBS201802, DICP I2020032]
- Yulin University [2021002, 2021009]
- Dalian National Laboratory for Clean Energy [2021002, 2021009]
- China Postdoctoral Science Foundation [2019M661141, 2020M680995]
Ask authors/readers for more resources
The study presents a scalable fabrication method for printable lithium ion micro-batteries with high energy density and exceptional flexibility, which can maintain a high capacity retention rate after multiple cycles. By using highly conductive and mechanically stable inks, LIMBs fabricated through multi-layer printing demonstrate stable areal capacity and energy density.
Pursuing high areal energy density and developing scalable fabrication strategies of micro-batteries are the key for the progressive printed microelectronics. Herein, the scalable fabrication of multi-layer printable lithium ion micro-batteries (LIMBs) with ultrahigh areal energy density and exceptional flexibility is reported, based on highly conductive and mechanically stable inks by fully incorporating the polyurethane binders in dibasic esters with high-conducting additives of graphene and carbon nanotubes into active materials to construct a cross-linked conductive network. Benefiting from relatively higher electrical conductivity (approximate to 7000 mS cm(-1)) and stably connected network of microelectrodes, the as-fabricated LIMBs by multi-layer printing display robust areal capacity of 398 mu Ah cm(-2), and remarkable areal energy density of 695 mu Wh cm(-2), which are much higher than most LIMBs reported. Further, the printed LIMBs show notable capacity retention of 88% after 3000 cycles, and outstanding flexibility without any structure degradation under various torsion states and folding angles. Importantly, a wearable smart bracelet, composed of a serially connected LIMBs pack, a temperature sensor, and a light-emitting diode, is realized for the automatic detection of body temperature. Therefore, this strategy of fabricating highly conductive and mechanically stable printable ink will open a new avenue for developing high-performance printable LIMBs for smart microelectronics.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available