Catalytic ozonation with disilicate-modified nZVI for quinoline removal in aqueous solution: Efficiency and heterogeneous reaction mechanism

Nanoscale zero-valent iron (nZVI) was not considered as an ideal candidate for catalytic ozonation process in aqueous media because of its drawbacks of rapid passivation, self-agglomeration and consequent loss of reactivity. In this study, a novel disilicate-modified nZVI (Si-nZVI) material, was prepared through a liquid-phase reducing method with hydrosoluble disilicate as a modifier. The optimal Si-nZVI catalyst (Si15-nZVI), with negligible iron leaching and a good tolerance in ozone water, showed favorable water-dispersibility to achieve a highly efficient ozonation catalysis for removing quinoline (91.9% removal efficiency). Compared to the nZVI, the Si-nZVI displayed satisfactory catalytic stability and benign reusability as well. It was revealed that -[Si-O-Fe]-OH groups on Si15-nZVI, as the dominating active centers, played an essential role to boost the adsorption and catalytic decomposition of O-3 in aqueous solution. This study demonstrates the suitability of SinZVI to catalytic ozonation process, and provides a prospective oxidation technology for decontamination.

Automated summary

This study demonstrates that Si-nZVI is a suitable candidate for catalytic ozonation process and offers a prospective oxidation technology for decontamination.