Structural and Optical Properties of MgO Thin Films Prepared by Dip-Coating Process: Effect of Thickness

Magnesium oxide (MgO) thin films with various thicknesses were successfully developed on glass substrates by sol-gel dip-coating technique. We have investigated the influence of the thickness (157, 352, and 915 nm), on the structural, optical, and morphological properties. X-ray diffraction study revealed that the deposited films were polycrystalline in nature with face-centered cubic structure along (200) and (220) directions. The transmittance was found to be decreased as the film thickness increased. In parallel, the optical band gap was found to be increased from 3.88 to 3.98 eV. The microstructure was found to be converted from inhomogeneous grains distribution with some voids in the surface to islands shapes distributed on homogeneous surface with increasing of the thickness. FTIR and EDX analysis confirmed the presence of Mg and oxygen elements. Also, the films were highly stoichiometric.

Automated summary

In this study, magnesium oxide (MgO) thin films with different thicknesses were successfully developed on glass substrates using the sol-gel dip-coating technique. The influence of film thickness on the structural, optical, and morphological properties was investigated. The results showed that the deposited films had a polycrystalline face-centered cubic structure along (200) and (220) directions. The transmittance decreased with increasing film thickness, while the optical band gap increased. The microstructure changed from inhomogeneous grains distribution to islands shapes distributed on a homogeneous surface with increasing film thickness.