Aging assessment of microplastics (LDPE, PET and uPVC) under urban environment stressors

The changes in the chemical structure, surface morphology and crystallinity are reported for three different polymers (LDPE, PET and uPVC) in microplastic form, after being artificially exposed to different aging agents that can affect microplastics in urban environments: ozone, UV-C, and solar radiation. In parallel to the laboratory experiments, the microplastics were exposed to real weathering conditions for three-months in a building rooftop located in the city of Porto (Portugal). By analysing the (virgin and aged) microplastic samples periodically through ATR-FTIR spectroscopy and estimating the Carbonyl Index, it was possible to sketch the aging degree evolution through time and identify the most aggressive agents for each polymer regarding the changes in their chemical structure. SEM and XRD measurements allowed to complement the ATR-FTIR results, giving a more complete picture of the effects of each treatment on each polymer and suggesting that ATR-FTIR measurements are not suffi-cient to correctly evaluate the aging degree of microplastics. The changes observed in the microplastic particles studied support the theory that microplastics in the environment undergo aging and change their characteristics through time, potentially affecting their behavior and intensifying their impacts. (c) 2021 Elsevier B.V. All rights reserved.

Automated summary

The study reported changes in the chemical structure, surface morphology, and crystallinity of three different polymers in microplastic form after being exposed to different aging agents. The results suggest that microplastics undergo aging in the environment, which may affect their behavior and intensify their impacts.