Effect of site hydrological conditions and soil aggregate sizes on the stabilization of heavy metals (Cu, Ni, Pb, Zn) by biochar

Biochar is a popular material that would effectively immobilize heavy metals in soil, which can greatly decrease the health risk of heavy metals. Although many previous studies have studied the immobilization of heavy metals by biochar, the influence of hydrological conditions on the immobilization effect is still not clear. This paper carried out column experiments to study the effect of fluctuating groundwater table on Cu, Ni, Pb, Zn distribution and speciation with the addition of biochar from pyrolysis of swine manure. Experimental results showed that biochar could significantly decrease the leaching toxicity of Cu and Ni by 24.4% and 44.7% respectively, while the immobilization effect of Pb and Zn was relatively insignificant. The average reduction percentage of bioavailable Cu was 14.5%, 39.5% and 33.3% in the unsaturated zone, fluctuating zone and saturated zone respectively, showing the better immobilization effect in the fluctuating zone and saturated zone. The residual fraction of heavy metals increased significantly after the addition of biochar, and the increase of residual fraction was larger in small soil aggregates. This study helped illustrate the influence of hydrological conditions and soil aggregate sizes on the stabilization effect of heavy metals by biochar, which could be used to guide the remediation process of sites contaminated by heavy metals. (c) 2021 Elsevier B.V. All rights reserved.

Automated summary

This study investigated the immobilization effect of biochar on heavy metals in soil, showing significant decreases in leaching toxicity of Cu and Ni but relatively insignificant effects on Pb and Zn. Better immobilization effects were observed in the fluctuating zone and saturated zone, with a significant increase in the residual fraction of heavy metals after the addition of biochar.