Unveiling the changes in urban atmospheric CO2 in the time of COVID-19 pandemic: A case study of Florence (Italy)

The outbreak of COVID-19 pandemic was accompanied by global mobility restrictions and slowdown in manufacturing activities. Accordingly, cities experienced a significant decrease of CO2 emissions. In this study, continuous measurements of CO2 fluxes, atmospheric CO2 concentrations and delta C-13-CO2 values were performed in the historical center of Florence (Italy) before, during and after the almost two-month long national lockdown. The temporal trends of the analyzed parameters, combined with the variations in emitting source categories (from inventory data), evidenced a fast response of flux measurements to variations in the strength of the emitting sources. Similarly, the delta C-13-CO2 values recorded the change in the prevailing sources contributing to urban atmospheric CO2, confirming the effectiveness of carbon isotopic data as geochemical tracers for identifying and quantifying the relative contributions of emitting sources. Although the direct impact of restriction measurements on CO2 concentrations was less clear due to seasonal trends and background fluctuations, an in-depth analysis of the daily local CO2 enhancement with respect to the background values revealed a progressive decrease throughout the lockdown phase at the end of the heating season (>10 ppm), followed by a net increase (ca. 5 ppm) with the resumption of traffic. Finally, the investigation of the shape of the frequency distribution of the analyzed variables revealed interesting aspects concerning the dynamics of the systems. (C) 2021 Elsevier B.V. All rights reserved.

Automated summary

During the COVID-19 pandemic, cities experienced a significant decrease in CO2 emissions, and a study in the historical center of Florence showed a fast response of CO2 fluxes and Delta C-13-CO2 values to changes in emitting sources. Although the direct impact was unclear, the daily local CO2 enhancement showed a gradual decrease during the lockdown phase and an increase with the resumption of traffic.