Journal
SCIENCE OF THE TOTAL ENVIRONMENT
Volume 796, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.scitotenv.2021.149042
Keywords
Sulfonamide; Soil; Non-extractable residues; Nitroxide radical; Interaction kinetics
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Funding
- Higher Education Institutional Excel-lence Programme of the Ministry of Human Capacities in Hungary
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This study used electron spin resonance spectroscopy to investigate the interaction kinetics of sulfonamides with model clay-humic acid suspensions. The results showed that sulfadiazine is immobilized due to covalent binding with humic acid, but not durably sequestered.
The characterization of the interaction of sulfonamides with soil is of particular interest in environmental risk and persistence assessment. In the present work electron spin resonance spectroscopy (ESR) was used to investigate the interaction kinetics of spin labelled sulfadiazine (SL-SDZ) with model clay-humic acid suspensions. The ESR spectra showed that SL-SDZ incubated with Leonardite humic acid (LHA) and Ca-hectorite as model clay was immobilized due to covalent binding of its aniline moiety to LHA. From the immobilization kinetics measured over a period of 1200 h a pseudo -first order reaction with a time constant of 82.6 +/- 25.0 h of covalent binding was determined. Additionally, SL-SDZ was strongly sorbed by LHA immediately after incubation but not durably sequestered. Compared to incubation without Ca-hectorite the covalent binding kinetics of SL-SDZ as well as its strong sorption were retarded. (c) 2021 Elsevier B.V. All rights reserved.
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